The maximum value of 〈 p 〉 and wavefunction.

Question

Consider the function v(1,2) =( [1s(1) 3s(2) + 3s(1) 1s(2)] [x(1) B(2) + B(1) a(2)] Which of the following statements is incorrect concerning p(1,2) ? a. W(1,2) is normalized. Ob. The function W(1,2) is symmetric with respect to the exchange of the space and the spin coordinates of the two electrons. OC. y(1,2) is an eigenfunction of the reference (or zero-order) Hamiltonian (in which the electron-electron repulsion term is ignored) of Li with eigenvalue = -5 hartree. d. The function y(1,2) is an acceptable wave function to describe the properties of one of the excited states of Lit. Oe. The function 4(1,2) is an eigenfunction of the operator S,(1,2) = S;(1) + S,(2) with eigenvalue zero.

Answer 1

Question

Chapter 3, Problem 3.41P

To determine

The maximum value of 〈p〉 and wavefunction.

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Consider the function v(1,2) =( [1s(1) 3s(2) + 3s(1) 1s(2)] [x(1) B(2) + B(1) a(2)] Which of the following statements is incorrect concerning p(1,2) ? a. W(1,2) is normalized. Ob. The function W(1,2) is symmetric with respect to the exchange of the space and the spin coordinates of the two electrons. OC. y(1,2) is an eigenfunction of the reference (or zero-order) Hamiltonian (in which the electron-electron repulsion term is ignored) of Li with eigenvalue = -5 hartree. d. The function y(1,2) is an acceptable wave function to describe the properties of one of the excited states of Lit. Oe. The function 4(1,2) is an eigenfunction of the operator S,(1,2) = S;(1) + S,(2) with eigenvalue zero.

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