(a)
To determine: The solvent that would be compatible with the acids and bases involved in the given reaction.
Interpretation: The solvent that would be compatible with the acids and bases involved in the given reaction is to be suggested.
Concept introduction: Solvent affects the solubility, stability, rate and path of the reaction. Generally, in acid-base reaction, acidic strength of an acid reactant should be higher than that of the solvent. If it is less than acidic strength of solvent, then base abstracts proton from the solvent rather than the acidic reactant.
(b)
To determine: The solvent that would be compatible with the acids and bases involved in the given reaction.
Interpretation: The solvent that would be compatible with the acids and bases involved in the given reaction is to be suggested.
Concept introduction: Solvent affects the solubility, stability, rate and path of the reaction. Generally, in acid-base reaction, acidic strength of an acid reactant should be higher than that of the solvent. If it is less than acidic strength of solvent, then base abstracts proton from the solvent rather than the acidic reactant.
(c)
To determine: The solvent that would be compatible with the acids and bases involved in the given reaction.
Interpretation: The solvent that would be compatible with the acids and bases involved in the given reaction is to be suggested.
Concept introduction: Solvent affects the solubility, stability, rate and path of the reaction. Generally in acid-base reaction, acidic strength of an acid reactant should be higher than that of the solvent. If it is less than acidic strength of solvent, then base abstracts proton from the solvent rather than the acidic reactant.
(d)
To determine: The solvent that would be compatible with the acids and bases involved in the given reaction.
Interpretation: The solvent that would be compatible with the acids and bases involved in the given reaction is to be suggested.
Concept introduction: Solvent affects the solubility, stability, rate and path of the reaction. Generally in acid-base reaction, acidic strength of an acid reactant should be higher than that of the solvent. If it is less than acidic strength of solvent, then base abstracts proton from the solvent rather than the acidic reactant.
(e)
To determine: The solvent that would be compatible with the acids and bases involved in the given reaction.
Interpretation: The solvent that would be compatible with the acids and bases involved in the given reaction is to be suggested.
Concept introduction: Solvent affects the solubility, stability, rate and path of the reaction. Generally in acid-base reaction, acidic strength of an acid reactant should be higher than that of the solvent. If it is less than acidic strength of solvent, then base abstracts proton from the solvent rather than the acidic reactant.
(f)
To determine: The solvent that would be compatible with the acids and bases involved in the given reaction.
Interpretation: The solvent that would be compatible with the acids and bases involved in the given reaction is to be suggested.
Concept introduction: Solvent affects the solubility, stability, rate and path of the reaction. Generally in acid-base reaction, acidic strength of an acid reactant should be higher than that of the solvent. If it is less than acidic strength of solvent, then base abstracts proton from the solvent rather than the acidic reactant.
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Chapter 2 Solutions
Organic Chemistry (9th Edition)
- Which of the following lists both acid species involved in the below equilibrium? Br– + CH2ClCOOH ⇌ HBr + CH2ClCOO– a. CH2ClCOOH & CH2ClCOO– b. CH2ClCOOH & Br– c. HBr & Br– d. CH2ClCOOH & HBr e. Br– & CH2ClCOO–arrow_forwardWhat is the acid dissociation constant (Ka) expression for the following reaction? CH3COOH+H2O=CH3COO-+H3Oarrow_forwardthis case, does it matter which ach (a) (b) Which definition, Brönsted-Lowry or Lewis, best describes what occurs during the reaction shown below? Explain why one definition is favored for this reaction. CI CI-AI DIHID CI CI-CI JC CI CI-AI POGIL WWW.POGIL.ORG Copyright © 2015 CI + CI-CI Label each reactant as acid and base in the reaction shown in #4a above.arrow_forward
- 18). The formulas and the structures of two acids are shown below. Which acid is a stronger acid? If the acid strength of the two acids is equal, say so. Cl2CHCOOH CH3COOH но но CI-C-C-OH н-с-с-он ČI Ką = 0.0324 Ką = 1.82 x 10-5 %3D a. Cl¿CHCOOH is a stronger acid than CH;COOH. b. CH;COOH is a stronger acid than CI½CHCOOH c. The two have equal acid strength. d. none of the abovearrow_forwardcch of the 4. Give the products from the following acid-base reactions and identify the acid and base on the left side, as well as the conjugate acid and conjugate base on the right side of the equation. NAOH a HO.arrow_forwardWhat reaction occurs as a hydrochloric acid solution is added to a solution containing equal concentrations of acetic acid and sodium acetate Group of answer choices CH3COOH + H+ → CH3COOH2+ CH3COOH + H+ → CH3CO+ + H2O 2CH3COO– + 2H+ → CH3COO + H2 CH3COO– + H+ → CH3COOHarrow_forward
- For the following reaction, draw the Lewis Dot structure for each reactant and product including any formal charges. Also identify the Lewis Acid and the Lewis Base for this reaction. CH3CH2CCH + NH2- -> CH3CH2CC- + NH3arrow_forwardHC H 36 46 15:11 29.0 ןו:5ר הה" HB/s Assignment 2.pdf 1. Identify the acids and bases in the following reactions: (a) CH3OH + H - CH,OH2 (b) CH3OH + NH2- - CH30- + NH3 Žnca +o (c) + ZnClz H3C HyC H 2. Rank the following substances in order of increasing acidity: H H C0H он H CH3CH. CH3CCH,CCH, CHyCOH Pentane-2,4-dione (pK, = 9) Phenol (pk, = 9.9) Acetone Acetic acid (pk,- 19.3) (pk, = 4.76) 3. List the following carboxylic acids in order from strongest acid to weakest acid: CH,CH;CH;COOH K,-1.52 x 10- CICH CH;CH;COOH K,-2.96 x 10 CH,CH;CHCOOH CH,CHCH;COOH ČI K1.39 10 K-8.9x 10 4. For the following compound, a. draw its conjugate acid. h. draw its conjugate base. H,NCH,COOH 5. List the following compounds in order from strongest acid to weakest acid: CH CH,COOH CH,OH CHCIOH 6. Which of the following are likely to act as Lewis acids and which as Lewis bases? Which might act both ways? (a) CH3CH,OH (b) (CH3)2NH (e) H3C+ (c) MgBrz (D (CHahP (d) (CH3)B IIIarrow_forwardFor each of the following reactions, highlight or circle the substance on the left hand side which is behaving as an acid and the substance on the right hand side which is its conjugate base. H2O + HCl ➡ H3O+ + Cl- CH3CO2H + OH ➡ CH3CO2- + H2O Justify each of your choices with concrete explanations.arrow_forward
- For the following reaction, draw the Lewis Dot structure for each reactant and product including any formal charges. Also identif Lewis Acid and the Lewis Base for this reaction. CH31 + OH- the I is iodine. - CH3OH + Iarrow_forwardWrite the equilibrium constant expression, K, for the following reaction. Please enter the compounds in the order given in the reaction. If either the numerator or denominator is blank, please enter 1 HF (aq) + H₂O(1) H3O*(aq) + F (aq) K =arrow_forwardIn the following reaction of tetrafluoroboric acid, HBF4, with acetate ion, C2H3O2-, the formation of tetrafluoroborate ion BF4-, and acetic acid, C2H4O2 is favored. HBF4 + C2H3O2- → BF4- + C2H4O2 Which is the weaker base, BF4- or acetate ion?arrow_forward
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning