Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 1, Problem 1.8P
Interpretation Introduction
Interpretation:
Two line-and-wedge structures of dichloromethane are to be drawn using the necessary models.
Concept introduction:
Line-and-wedge is one of the types of representation of a compound in a three dimensional fashion. In this type of representation, solid lines indicate the bonds within the plane, wedge line indicates the bond above the plane and dashed line indicates the bond below the plane.
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Draw a bond-line structure that best matches the molecule below. (White = hydrogen; yellow = fluorine; green = chlorine; red = bromine)
Draw the shapes of the following molecules and ions in 3-dimension. Show clearly any lone pairs of electrons on the central atom, state the number of bond pairs and lone pairs of electrons on the central atom and name the shape of the molecule or ion.
(a) SiCI4, silicon tetrachloride
(b) PBr3, phosphorus tribromide
(c) CI2O, dichlorine oxide
Provide everything stated in the instructions for each compound.
Draw the shapes of the following molecules and ions in 3-dimension. Show clearly any lone pairs of electrons on the central atom, state the number of bond pairs and lone pairs of electrons on the central atom and name the shape of the molecule or ion.
(a) AIH4-, aluminium hydride ion
(b) CH3-, methyl carbanion
(c) POCl3, phosphorus oxychloride
Provide everything stated in the instructions for each compound.
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - Prob. 1.1PCh. 1 - Prob. 1.2PCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.4PCh. 1 - Prob. 1.5PCh. 1 - Prob. 1.6PCh. 1 - Prob. 1.7PCh. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Prob. 1.21APCh. 1 - Prob. 1.22APCh. 1 - Prob. 1.23APCh. 1 - Prob. 1.24APCh. 1 - Prob. 1.25APCh. 1 - Prob. 1.26APCh. 1 - Prob. 1.27APCh. 1 - Prob. 1.28APCh. 1 - Prob. 1.29APCh. 1 - Prob. 1.30APCh. 1 - Prob. 1.31APCh. 1 - Prob. 1.32APCh. 1 - Prob. 1.33APCh. 1 - Prob. 1.34APCh. 1 - Prob. 1.35APCh. 1 - Prob. 1.36APCh. 1 - Prob. 1.37APCh. 1 - Prob. 1.38APCh. 1 - Prob. 1.39APCh. 1 - Prob. 1.40APCh. 1 - Prob. 1.41APCh. 1 - Prob. 1.42APCh. 1 - Prob. 1.43APCh. 1 - Prob. 1.44APCh. 1 - Prob. 1.45APCh. 1 - Prob. 1.46APCh. 1 - Prob. 1.47APCh. 1 - Prob. 1.48APCh. 1 - Prob. 1.49AP
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- Draw a line-bond structure for the following molecule, making sure to properly indicate 3D arrangement using solid and dashed wedges. (gray spheres = carbon, white = hydrogen, red = oxygen.)arrow_forwardExcept for nitrogen, the elements of Group 5A(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give, successively, PCI4F, PCI3F2, .. PF5. (a) Given the relative sizes of F and CI, would you expect the first two F substitutions to be at axial or equatorial positions? O axial equatorial This answer has not been graded yet. (b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.) PCIF4 PCI3F2 PCI2F3 PF5 PCI4Farrow_forwardReport all your results by using significant figures and use dimensional analysis. i) AsF3, (ii) BrF3, (iii) ClO3-, (iv) BrO2- Answer the following questions for the molecules given above: a) Draw the Lewis structure for each of the following molecules or ions. b) Predict their electron-domain and molecular geometries. c) Assign oxidation numbers and formal charges to each atom. d) Is it polar or nonpolar? e) Comment on the bond angle of each compound. f) Write the hybridization of the central atom in each molecule.arrow_forward
- CTQ 7: Why is it incorrect to describe the process of boiling as 2H,0(1) → 2H,(g) + 0,(g)?arrow_forward(d) A substance has the molecular formula C4H,N. Is there any likelihood that this material contains a triple bond? Provide reasons.arrow_forwardExcept for nitrogen, the elements of Group 5A(15) all form pentafluorides, and most form pentachlorides. The chlorine atoms of PCl₅ can be replaced with fluorine atoms one at a timeto give, successively, PCl₄F, PCl₃F₂, ... , PF₅. (a) Given the sizesof F and Cl, would you expect the first two F substitutions to beat axial or equatorial positions? Explain. (b) Which of the five fluorine-containing molecules have no dipole moment?arrow_forward
- (c) How does the energy and length of the carbon–oxygen bond in CH3OH(ℓ) compare with the carbon–oxygen distance in carbon monoxide? Explainarrow_forwardWhat exactly is meant by the term "homogeneous structure"?arrow_forwardH H- Br -H •S: Consider the Lewis structure provided above. Answer the following questions about the compound in the provided boxes. (A) What is the class formula (AXE₂)? Note that you do not need to use subscripts. type your answer... (B) What is the steric number? type your answer... (C) What is the electron geometry? type your answer... (D) What is the molecular geometry? type your answer... (E) What is the hybridization of the central atom? Note that you do not need to use superscripts type your answer...arrow_forward
- Draw the shapes of the following molecules and ions in 3-dimension. Show clearly any lone pairs of electrons on the central atom, state the number of bond pairs and lone pairs of electrons on the central atom and name the shape of the molecule or ion. (a) PH4+, phosphonium ion (b) PBr5, phosphorus pentabromide (c) H3O+, oxonium ion Provide everything stated in the instructions for each compound.arrow_forwardUse VSEPR theory to predict the shape of this molecule (POC13) and indicate any deviation from the bond angle(s) expected from a regular arrangement of repulsion axes. Show all the steps took to arrive at answer 4 to five sentencesarrow_forwardDraw Lewis structures for each of the following compounds. In each case, specify the number of valence electrons surrounding the central atom. (Assign lone pairs and radical electrons where appropriate.) (Assume the central atom does not contain an expanded octet.) (a) bromine dioxide (BrO2) (b) beryllium bromide (BeBr2) (c) phosphorus pentafluoride (PF5)arrow_forward
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