Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 1, Problem 1.41AP
Interpretation Introduction

Interpretation:

The reason corresponding to the fact that, even though the CCl bond dipole is large, the dipole moment of carbon tetrachloride, CCl4, is zero has to be explained.

Concept introduction:

The quantity that is used to measure the uneven distribution of electrons around the atoms of a compound that possess the covalent bonds is known as dipole moment. It is denoted by μ. The dipole moment is the calculated by the multiplication of the magnitude of separated charges, q, with the vector, r, from positive to negative charge regions. The expression for dipole moment is given as,

μ=qr

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Molecules can be polar because of the unsymmetrical distribution of electrons. The dipole moment, μ Q r μ=Q×r The SI unit of dipole moment is the coulomb-meter (C⋅m), but another common unit is the debye (D). The two are related as 3.336×10^−30 C⋅m=1 D The percent ionic character is a comparison of the measured dipole moment of the bond to the expected dipole moment if electrons are instead transferred: %ionic character=measured dipole/if electrons transferred×100% The dipole moment if electrons are completely transferred is one for which a full unit of charge (1.60×10^−19 C) exists on each end of the bond. The dipole measured for HI is 0.380 D. The bond distance is 161 pm. What is the percent ionic character of the HI bond? Express your answer as a percent to three significant figures.   Describe the molecular dipole of OCl2.
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