Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
Question
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Chapter 1, Problem 1.26AP
Interpretation Introduction

(a)

Interpretation:

The electronic configuration of the chlorine atom is to be stated.

Concept introduction:

The arrangement of electrons in an atom is represented by the electronic configuration of the atom. The electronic configuration is written by following certain set of rules which arrange the orbitals of the atom in their correct order.

Interpretation Introduction

(b)

Interpretation:

The electronic configuration of the silicon atom (Si) is to be stated. The valence electrons and the valence orbitals of Si are to be stated.

Concept introduction:

The arrangement of electrons in an atom is represented by the electronic configuration of the atom. The electronic configuration is written by following certain set of rules which arrange the orbitals of the atom in their correct order.

Interpretation Introduction

(c)

Interpretation:

The electronic configuration of the argon atom is to be stated.

Concept introduction:

The arrangement of electrons in an atom is represented by the electronic configuration of the atom. The electronic configuration is written by following certain set of rules which arrange the orbitals of the atom in their correct order.

Interpretation Introduction

(d)

Interpretation:

The electronic configuration of the magnesium atom is to be stated.

Concept introduction:

The arrangement of electrons in an atom is represented by the electronic configuration of the atom. The electronic configuration is written by following certain set of rules which arrange the orbitals of the atom in their correct order.

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Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Determine the number of valence electrons and give the electronic confi guration of the valence electrons of each element: (a) nitrogen; (b) potassium.
When a nonmetal oxide reacts with water, it forms an oxoacid with the same oxidation number as the nonmetal. Give the name and formula of the oxide used to prepare each of these oxoacids: (a) hypochlorous acid; (b) chlorous acid; (c) chloric acid; (d) perchloric acid; (e) sulfuric acid; (f ) sulfurous acid; (g) nitric acid; (h) nitrous acid; (i) carbonic acid; ( j) phosphoric acid.
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