Essential University Physics: Volume 2 (3rd Edition)
Essential University Physics: Volume 2 (3rd Edition)
3rd Edition
ISBN: 9780321976420
Author: Richard Wolfson
Publisher: PEARSON
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Chapter 37, Problem 62P

(a)

To determine

The expression for Umin from the Morse potential.

(b)

To determine

The separation rmin at the minimum energy.

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The potential energy of a system of two atoms is given by the relation U =-A/r + B/r10 A stable molecule is formed with the release of 8 eV energy when the interatomic distance is 2.8 Å. Find A and B and the force needed to dissociate this molecule into atoms and the interatomic distance at which the dissociation occurs.
One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential,                          U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.
One model for the potential energy of a two-atom molecule, where the atoms are separated by a distance r, is U(r) = Uo[(¹) ¹2 – ( )²] where ro = 0.8 nm and U₁ = 6.1 eV. Note: 1 eV = 1.6 × 10-19 J. Some helpful units: [Force] = eV/nm [Energy] = eV [distance] = nm Equilibrium Distance What is the distance between the atoms when the molecule is in stable equilibrium? Click here for a hint T'eq Hint: Hint: Hint: Hint: Hint: Hint: Force If the distance between the atoms increases from equilibrium by r₁ = 0.35 nm, then what is the force from one atom on the other associated with this potential energy? (Enter your answer as postive if they repel each other, and negative if they attract.) Fr(req+r₁) Hint: Hint: 0.89105934nm Kinetic Energy Hint: The atoms are oscillating back and forth. The maximum separation of the atoms is r₂ = 2 nm. What is the kinetic energy of the atoms when they are separated by the equilibrium distance? Click here for a hint K(req) Hint: Hint: = -1.288eV/nm 3.99eV

Chapter 37 Solutions

Essential University Physics: Volume 2 (3rd Edition)

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