a) Interpretation: Whether the compound shown will be a good dienophile or not is to be predicted. Concept introduction: In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond. To predict: Whether the compound shown will be a good dienophile or not.

Question

Q1. Write the product for each of the following Diels-Alder reactions. осн, CH CHE OCH3

Answer 1

Question

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

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Q1. Write the product for each of the following Diels-Alder reactions. осн, CH CHE OCH3

Draw the structural formula of the product of the reaction shown below. + H₂O AAVIL H₂SO4 • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. Sn [F Ⓡ ChemDoodle

Use arrows to predict the final favored product of the following Diels-Alder reaction. Use the step-wise mechanism to predict the final product of the following reaction. Show stereochemistry at stereogenic centers. NaBH4 CH;OH Use the step-wise mechanism to predict the product of the following reaction. (Excess) H.

Answer 2

Question

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Expert Solution & Answer

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Answer 3

Question

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Expert Solution & Answer

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Answer 4

Question

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Expert Solution & Answer

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Answer 5

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 6

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 7

Chapter 14.5, Problem 8P

Interpretation Introduction

a)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 8

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 9

Interpretation Introduction

b)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 10

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 11

Interpretation Introduction

c)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 12

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 13

Interpretation Introduction

d)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 14

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 15

Interpretation Introduction

e)

Interpretation:

Whether the compound shown will be a good dienophile or not is to be predicted.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond.

To predict:

Whether the compound shown will be a good dienophile or not.

Answer 16

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Answer 17

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Answer 23

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Answer 27

Ch. 14.1 - Prob. 1P Ch. 14.2 - Give the structures of both 1, 2 and 1, 4 adducts...Ch. 14.2 - Prob. 3P Ch. 14.2 - Give the structures of both 1, 2 and 1, 4 adducts...Ch. 14.3 - Prob. 5P Ch. 14.3 - Prob. 6P Ch. 14.5 - Predict the product of the following Dielsâ€“Alder...Ch. 14.5 - Prob. 8P Ch. 14.5 - Which of the following dienes have an s-cis...Ch. 14.5 - Predict the product of the following Dielsâ€“Alder...

Solution Summary: The author explains that the compound shown will be a good dienophile.

Chapter 14 Solutions