Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 1, Problem 1.30SP
- a. Both PCl3 and PCl5 are stable compounds Draw Lewis structures for these two compounds
- b. NCl3 is a known compound, but all attempts to synthesize NCl5 have failed Draw Lewis structures for NCl3 and a hypothetical NCl5, and explain why NCl5 is an unlikely structure.
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2. Avogadro does not "waste" his time drawing a Lewis structure before
determining the shape of PF3. He thinks that the shape of PF3 must be trigonal
planar because there are three fluorine atoms bonded to the central
phosphorus atom.
a. Draw the Lewis structure for PF3.
b. Was Avogadro's answer for the shape of a PF3 molecule correct? Explain
c. Why is it important to draw the Lewis structure for a molecule before
identifying the shape of the molecule?
2. Avogadro does not "waste" his time drawing a Lewis structure before
determining the shape of PF3. He thinks that the shape of PF3 must be trigonal
planar because there are three fluorine atoms bonded to the central
phosphorus atom.
a. Draw the Lewis structure for PF3.
b. Was Avogadro's answer for the shape of a PF3 molecule correct? Explain
c. Why is it important to draw the Lewis structure for a molecule before
identifying the shape of the molecule?
3. Draw the Lewis structure of ozone, O3. Describe why ozone has a bent shape
instead of a linear shape.
A compound is being tested for use as a rocket propellant. The analysis showed that this compound contained 18.54% F, 34.61% Cl, and 46.85% O.a. Suppose the molecular formula is the same as the empirical formula, describing the Lewis structure for this moleculeb. Use the VSEPR theory to predict the structure of this moleculec. List the three anions of the elements according to their increment in the radius of the ion.
Ar F = 19, Cl = 35,5, O= 16
Chapter 1 Solutions
Organic Chemistry (9th Edition)
Ch. 1.2C - a. Nitrogen has relatively stable isotopes...Ch. 1.4 - Draw Lewis structures for the following compounds....Ch. 1.5 - Write Lewis structures for the following molecular...Ch. 1.5 - Circle any lone pairs (pairs of nonbonding...Ch. 1.6 - Use electronegativities to predict the direction...Ch. 1.8 - Prob. 1.6PCh. 1.9B - Draw the important resonance forms for the...Ch. 1.9B - Prob. 1.8PCh. 1.9B - Prob. 1.9PCh. 1.9B - Use resonance structures to identify the areas of...
Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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