Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 1, Problem 11CTQ
Interpretation Introduction
Interpretation:
The value“close to
Concept Introduction:
Molecular geometry is the
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Bond Angles in an Organic
Molecule II
The random letter labels in this diagram of allylcyanide are to
be associated with the corresponding bond angle (or other
property of the nearest atom).
H
H
H
dc
H-
a
H
b
C=N
Match the following (but do not select any individual letter
more than once):
CCC angle ~109.5°
HCH angle ~120º
CCC angle ~120°
HCH angle ~109.5°
bond angle ~180°
3.
3
3
•
According to VSEPR, what is the approximate value of the bond angle #1? Think 3D.
7)
Molecular Geometry/
Electron-Group Geometry
Total
Valence
Formula
Rough Lewis Structure
Electrons
Molecular Geometry:
I3
Electron-Group Geo.:
(Include formal charges other than 0.)
More
soluble
in
Bond Polarity (AEN)
Molecule Polarity
hexane or water?
8)
Molecular Geometry/
Electron-Group Geometry
Total
Valence
Formula
Rough Lewis Structure
Electrons
Molecular Geometry:
SİF4
Electron-Group Geo.:
(Include formal charges other than 0.)
More
soluble
in
Bond Polarity (AEN)
Molecule Polarity
hexane or water?
8.
Chapter 1 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 1 - (E) What does the number (+Z) at the center of...Ch. 1 - Prob. 2CTQCh. 1 - Prob. 3CTQCh. 1 - Prob. 4CTQCh. 1 - Prob. 5CTQCh. 1 - Prob. 6CTQCh. 1 - Prob. 7CTQCh. 1 - You hear a student from a nearby group say that...Ch. 1 - Use VSEPR to explain why the HBH bond angle of BH3...Ch. 1 - Both the HCH and HCO bond angles of H2CO...
Ch. 1 - Prob. 11CTQCh. 1 - Consider the following flat drawing of methane...Ch. 1 - Use VSEPR to assign a value of (close to) 109.5,...Ch. 1 - A student draws the picture of ammonia (NH3) in...Ch. 1 - Prob. 15CTQCh. 1 - How many central atoms does the molecule H2NCH3...Ch. 1 - Indicate the bond angle and shape about each...Ch. 1 - Explain how there can be two kinds of bent:...Ch. 1 - A student makes the following statement: “The...Ch. 1 - A student who missed this class needs to know how...Ch. 1 - Prob. 1ECh. 1 - Prob. 2ECh. 1 - Consider the incomplete valence shell...Ch. 1 - How many valence electrons does a neutral a. K...Ch. 1 - Consider the molecules AlCl3 (aluminum chloride)...Ch. 1 - Draw an example of a bent molecule with a bond...Ch. 1 - Label each atom marked with an arrow with the...Ch. 1 - a model of each of the following molecules: a....
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- A student who missed this class needs to know how to predict the bond angles and shape of amolecule from looking at its bond-line representation. Write a concise but complete explanationfor this student.arrow_forwardDetermine the number of hydrogen atoms connected to each carbon atom: The bond-line structure of a compound has a SMILES string of CC1CCN(CC1N(C)C2-NC-NC3=C2C=CN3)C(=O)CC#N. All the carbon atoms of the compound are highlighted and labeled a through p. To b n d > C > Save for Later 15 4 g 09 h > > > > - k 1 > > > > E n o Р 3 Attempts: 0 of 3 used Submit Answerarrow_forwardA student who missed this class needs to know how to predict the bond angles and shape of a molecule from looking at its line representation. Write a concise but complete explanation for this student.arrow_forward
- Provide the following bond angles that corrsespond to each letter. Bond angle of a: Bond angle of b: Bond angle of c:arrow_forwardThe carbon atoms in the molecule below are labeled 1-8. Which C-C-C bond angle in the molecule would be approximately 120?arrow_forwardMolecule #7 BrF4* Calculate the number of valence electrons Draw the three-dimensional structure of the molecule using the "wedge and dash" notation. Our logic for this choice is: The formal charge on F is Estimate F-Br-F bond angle Calculate the number of valence electrons Draw the three-dimensional structure of the molecule using the "wedge and dash" notation. Our logic for this choice is: Draw the Lewis Structure below The molecular geometry is: This molecule is polar nonpolar (Circle your choice.) The formal charge on Br is The hybridization of Br is Molecule #8 XeOF4 Draw the Lewis Structure below The molecular geometry is: This molecule is polar nonpolar (Circle your choice.) The formal charge on Xe is The hybridization of Xe is The formal charge on O is Estimate F-Xe-F bond anglearrow_forward
- These molecules are called constitutional (or structural) isomers because they share the same chemical formula but have different patterns of atomic connectivity. Draw as many constitutional isomers as you can for C5H8 in bond-line notation. It may be helpful to draw a Lewis Structure for one of the isomers first.arrow_forwardFor each of the carbon-carbon double bonds below, state which of the following terms appropriately describes the configuration of the bond: cis, trans, E, Z. If none of the terms are appropriate, write "none". You do not have to name the compounds. Note: More than one term may be appropriate for a particular bond. ): a) b) c) H HO OHarrow_forwardDraw a bond-line structure that best matches the molecule below. (White = hydrogen; yellow = fluorine; green = chlorine; red = bromine)arrow_forward
- bond dipole moments can be added together to obtain the molecular dipole moment true or falsearrow_forwardDraw each molecule with its correct geometry in 3D and indicate the direction of the molecule's overall dipole, if none label it as zero.arrow_forward) Bean hexene is an odor compound used in cosmetics and cleaners. It is also known as leguminal. Its formula is: CH3CH2CHCHCH2CH2OCHCH2CH3 | OCH3 Please draw a Lewis structure for this compound with CORRECT GEOMETRY (use dashes and wedges!) Label all pi bonds in the molecule (if there are any) Indicate the bond angles for the red highlighted section of the molecule. (hint: you may want to keep the main carbon chain in-plane with the page for clarity) For this question, you don’t need to draw out the orbitals.arrow_forward
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