Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Chapter 4.5, Problem 4.44P
To determine
The proof that the wave function given by equation 4.197 satisfies Schrodinger’s equation.
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I have an electron that I want to put in a rigid box. How small do I need to make the box so that the speed of my electron in its ground state inside the box will be equal to the speed of light? Include a sketch of U(x) and ?(x).
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Consider the function
v(1,2) =(
[1s(1) 3s(2) + 3s(1) 1s(2)]
[x(1) B(2) + B(1) a(2)]
Which of the following statements is incorrect concerning p(1,2) ?
a.
W(1,2) is normalized.
Ob.
The function W(1,2) is symmetric with respect to the exchange of the space and the spin coordinates of the two electrons.
OC.
y(1,2) is an eigenfunction of the reference (or zero-order) Hamiltonian (in which the electron-electron repulsion term is ignored) of Li with
eigenvalue = -5 hartree.
d.
The function y(1,2) is an acceptable wave function to describe the properties of one of the excited states of Lit.
Oe.
The function 4(1,2) is an eigenfunction of the operator S,(1,2) = S;(1) + S,(2) with eigenvalue zero.
2.4.
A particle moves in an infinite cubic potential well described by:
V (x1, x2) = {00
12=
if 0 ≤ x1, x2 a
otherwise
1/2(+1)
(a) Write down the exact energy and wave-function of the ground state.
(2)
(b) Write down the exact energy and wavefunction of the first excited states and specify their
degeneracies.
Now add the following perturbation to the infinite cubic well:
H' = 18(x₁-x2)
(c) Calculate the ground state energy to the first order correction.
(5)
(d) Calculate the energy of the first order correction to the first excited degenerated state.
(3)
(e) Calculate the energy of the first order correction to the second non-degenerate excited
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Chapter 4 Solutions
Introduction To Quantum Mechanics
Ch. 4.1 - Prob. 4.1PCh. 4.1 - Prob. 4.3PCh. 4.1 - Prob. 4.4PCh. 4.1 - Prob. 4.5PCh. 4.1 - Prob. 4.6PCh. 4.1 - Prob. 4.7PCh. 4.1 - Prob. 4.8PCh. 4.1 - Prob. 4.9PCh. 4.1 - Prob. 4.10PCh. 4.1 - Prob. 4.11P
Ch. 4.2 - Prob. 4.12PCh. 4.2 - Prob. 4.13PCh. 4.2 - Prob. 4.14PCh. 4.2 - Prob. 4.15PCh. 4.2 - Prob. 4.16PCh. 4.2 - Prob. 4.17PCh. 4.2 - Prob. 4.18PCh. 4.2 - Prob. 4.19PCh. 4.2 - Prob. 4.20PCh. 4.3 - Prob. 4.21PCh. 4.3 - Prob. 4.22PCh. 4.3 - Prob. 4.23PCh. 4.3 - Prob. 4.24PCh. 4.3 - Prob. 4.25PCh. 4.3 - Prob. 4.26PCh. 4.3 - Prob. 4.27PCh. 4.4 - Prob. 4.28PCh. 4.4 - Prob. 4.29PCh. 4.4 - Prob. 4.30PCh. 4.4 - Prob. 4.31PCh. 4.4 - Prob. 4.32PCh. 4.4 - Prob. 4.33PCh. 4.4 - Prob. 4.34PCh. 4.4 - Prob. 4.35PCh. 4.4 - Prob. 4.36PCh. 4.4 - Prob. 4.37PCh. 4.4 - Prob. 4.38PCh. 4.4 - Prob. 4.39PCh. 4.4 - Prob. 4.40PCh. 4.4 - Prob. 4.41PCh. 4.5 - Prob. 4.42PCh. 4.5 - Prob. 4.43PCh. 4.5 - Prob. 4.44PCh. 4.5 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - Prob. 4.51PCh. 4 - Prob. 4.52PCh. 4 - Prob. 4.53PCh. 4 - Prob. 4.54PCh. 4 - Prob. 4.55PCh. 4 - Prob. 4.56PCh. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - Prob. 4.59PCh. 4 - Prob. 4.61PCh. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - Prob. 4.64PCh. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Prob. 4.70PCh. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Prob. 4.75PCh. 4 - Prob. 4.76P
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Similar questions
- Problem 7. 1. Calculate the energy of a particle subject to the potential V(x) = Vo + câ?/2 if the particle is in the third excited state. 2. Calculate the energy eigenvalues for a particle moving in the potential V(x) = câ2/2+ bx. %3!arrow_forwardProblem 4.25 If electron, radius [4.138] 4πεmc2 What would be the velocity of a point on the "equator" in m /s if it were a classical solid sphere with a given angular momentum of (1/2) h? (The classical electron radius, re, is obtained by assuming that the mass of the electron can be attributed to the energy stored in its electric field with the help of Einstein's formula E = mc2). Does this model make sense? (In fact, the experimentally determined radius of the electron is much smaller than re, making this problem worse).arrow_forwardProblem 2.2 Show that E must exceed the minimum value of V (x), for every normalizable solution to the time-independent Schrödinger equation. What is the classical analog to this statement? Hint: Rewrite Equation 2.5 in the form d² 2m [V(x) - E]; dx² if E < Vmin, then and its second derivative always have the same sign-argue that such a function cannot be normalized. h² d² 2m dx² + Vy = Ev. (2.5)arrow_forward
- Problem 3.36. Consider an Einstein solid for which both N and q are much greater than 1. Think of each oscillator as a separate "particle." (a) Show that the chemical potential is N+ - kT ln N (b) Discuss this result in the limits N > q and N « q, concentrating on the question of how much S increases when another particle carrying no energy is added to the system. Does the formula make intuitive sense?arrow_forwardThe following problem arises in quantum mechanics (see Chapter 13, Problem 7.21). Find the number of ordered triples of nonnegative integers a, b, c whose sum a+b+c is a given positive integer n. (For example, if n = 2, we could have (a, b, c) = (2, 0, 0) or (0, 2, 0) or (0, 0, 2) or (0, 1, 1) or (1, 0, 1) or (1, 1, 0).) Hint: Show that this is the same as the number of distinguishable distributions of n identical balls in 3 boxes, and follow the method of the diagram in Example 5.arrow_forwardSolve the time-independent Schrödinger equation with appropriate boundary conditions for an infinite square well centered at the origin [V (x) = 0, for -a/2 < x < +a/2; V (x) = 00 otherwise]. Check that your allowed energies are consistent with mine (Equation 2.23), and confirm that your y's can be obtained from mine (Equation 2.24) by the substitution x x - a/2.arrow_forward
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