Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 24.9C, Problem 24.19P

(a)

Interpretation Introduction

To determine: The structure of the phenylthiohydantoin derivative of alanine.

Interpretation: The structure of the phenylthiohydantoin derivative of alanine is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the  peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(b)

Interpretation Introduction

To determine: The structure of the phenylthiohydantoin derivative of tryptophan.

Interpretation: The structure of the phenylthiohydantoin derivative of tryptophan is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the  peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(c)

Interpretation Introduction

To determine: The structure of the phenylthiohydantoin derivative of lysine.

Interpretation: The structure of the phenylthiohydantoin derivative of lysine is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the  peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(d)

Interpretation Introduction

To determine: The structure of the phenylthiohydantoin derivative of proline.

Interpretation: The structure of the phenylthiohydantoin derivative of proline is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the  peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

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Chapter 24 Solutions

Organic Chemistry (9th Edition)

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