a) (CH 3 ) 3 C CO 2 H from (CH 3 ) 3 CCl Interpretation: How (CH 3 ) 3 COOH can be prepared from (CH 3 ) 3 CCl is to be shown. Concept introduction: The alkyl halide is converted into a Grignard reagent by treatment with Mg in ether. The Grignard reagent when treated with CO 2 followed by hydrolysis yield carboxylic acid . To show: How to prepare (CH 3 ) 3 COOH from (CH 3 ) 3 CCl.

Question

Write the products of the following acid-base reactions: (a) CH3OH + H2SO4 ² ? (b) CH3OH + NANH2 2 ? (c) CH3NH3+ Cl- + NaOH ?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20.5, Problem 10P

Interpretation Introduction

a) (CH₃)₃C CO₂H from (CH₃)₃CCl

Interpretation:

How (CH₃)₃COOH can be prepared from (CH₃)₃CCl is to be shown.

Concept introduction:

The alkyl halide is converted into a Grignard reagent by treatment with Mg in ether. The Grignard reagent when treated with CO₂ followed by hydrolysis yield carboxylic acid.

To show:

How to prepare (CH₃)₃COOH from (CH₃)₃CCl.

Interpretation Introduction

b) CH₃CH₂CH₂CO₂H from CH₃CH₂CH₂Br

Interpretation:

How CH₃CH₂CH₂COOH can be prepared from CH₃CH₂CH₂Br is to be shown.

Concept introduction:

The displacement of bromine in the alkyl halide by a cyanide group and the hydrolysis of the nitrile obtained will yield the acid required.

To show:

How to prepare CH₃CH₂CH₂COOH from CH₃CH₂CH₂Br.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20.5, Problem 10P

Interpretation Introduction

a) (CH₃)₃C CO₂H from (CH₃)₃CCl

Interpretation:

How (CH₃)₃COOH can be prepared from (CH₃)₃CCl is to be shown.

Concept introduction:

The alkyl halide is converted into a Grignard reagent by treatment with Mg in ether. The Grignard reagent when treated with CO₂ followed by hydrolysis yield carboxylic acid.

To show:

How to prepare (CH₃)₃COOH from (CH₃)₃CCl.

Interpretation Introduction

b) CH₃CH₂CH₂CO₂H from CH₃CH₂CH₂Br

Interpretation:

How CH₃CH₂CH₂COOH can be prepared from CH₃CH₂CH₂Br is to be shown.

Concept introduction:

The displacement of bromine in the alkyl halide by a cyanide group and the hydrolysis of the nitrile obtained will yield the acid required.

To show:

How to prepare CH₃CH₂CH₂COOH from CH₃CH₂CH₂Br.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20.5, Problem 10P

Interpretation Introduction

a) (CH₃)₃C CO₂H from (CH₃)₃CCl

Interpretation:

How (CH₃)₃COOH can be prepared from (CH₃)₃CCl is to be shown.

Concept introduction:

The alkyl halide is converted into a Grignard reagent by treatment with Mg in ether. The Grignard reagent when treated with CO₂ followed by hydrolysis yield carboxylic acid.

To show:

How to prepare (CH₃)₃COOH from (CH₃)₃CCl.

Interpretation Introduction

b) CH₃CH₂CH₂CO₂H from CH₃CH₂CH₂Br

Interpretation:

How CH₃CH₂CH₂COOH can be prepared from CH₃CH₂CH₂Br is to be shown.

Concept introduction:

The displacement of bromine in the alkyl halide by a cyanide group and the hydrolysis of the nitrile obtained will yield the acid required.

To show:

How to prepare CH₃CH₂CH₂COOH from CH₃CH₂CH₂Br.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20.5, Problem 10P

Interpretation Introduction