Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Question
Chapter 18.13, Problem 22P
Interpretation Introduction
Interpretation:
The relationship between the major and minor products of the given reaction as enantiomers or diastereomers is to be identified.
Concept introduction:
The organic compounds that are found to be non-superimposable on their mirror images are called as enantiomers.
On the other hand, the compounds that are not mirror images of each other are called as diastereomers.
The enantiomer of a compound has an opposite configuration.
Diastereomers of a compound have at least one stereogenic center with same configuration and at least one stereogenic center with opposite configuration.
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Problem 5.37
Compare the physical properties of the three stereoisomers of 1,3-dimethylcyclopentane.
A
B
C
three stereolsomers of 1,3-dimethylcyclopentane
a. How do the boiling points of A and B compare? What about those of A and C?
b. Characterize a solution of each of the following as optically active or optically inactive:
pure A; pure B; pure C; an equal mixture of A and B; an equal mixture of A and C.
c. A reaction forms a 1:1:1 mixture of A, B, and C. If this mixture is distilled, how many
fractions would be obtained? Which fractions would be optically active and which
would be optically inactive?
Problem 5.25
If the two stereogenic centers of a compound are R,S in configuration, what are the R,S
assignments for its enantiomer and two diastereomers?
Problem 5.16
Label each stereogenic center as R or S.
e.
HO,
HO H
f.
Chapter 18 Solutions
Organic Chemistry - Standalone book
Ch. 18.1 - Prob. 1PCh. 18.1 - Prob. 2PCh. 18.3 - Prob. 3PCh. 18.4 - Prob. 4PCh. 18.4 - Prob. 5PCh. 18.6 - Prob. 6PCh. 18.7 - Prob. 7PCh. 18.7 - Prob. 8PCh. 18.7 - Prob. 9PCh. 18.8 - Prob. 10P
Ch. 18.8 - Prob. 11PCh. 18.8 - Prob. 12PCh. 18.9 - Prob. 13PCh. 18.10 - Prob. 14PCh. 18.10 - Prob. 15PCh. 18.11 - Problem 18.16 The product of the following...Ch. 18.11 - Prob. 17PCh. 18.12 - Problem 18.18 What other combination of ylide and...Ch. 18.12 - Prob. 19PCh. 18.12 - Prob. 20PCh. 18.12 - Prob. 21PCh. 18.13 - Prob. 22PCh. 18 - (a) Write structural formulas and provide IUPAC...Ch. 18 - Each of the following aldehydes and ketones is...Ch. 18 - The African dwarf crocodile secretes a volatile...Ch. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - Prob. 31PCh. 18 - Each of the following reaction has been reported...Ch. 18 - Prob. 33PCh. 18 - On standing in 17O-labeled water, both...Ch. 18 - Prob. 35PCh. 18 - Prob. 36PCh. 18 - The OH groups at C-4 and C-6 of methyl ...Ch. 18 - Prob. 38PCh. 18 - Prob. 39PCh. 18 - The sex attractant of the female winter moth has...Ch. 18 - Prob. 41PCh. 18 - Prob. 42PCh. 18 - Prob. 43PCh. 18 - Suggest a reasonable mechanism for each of the...Ch. 18 - Prob. 45PCh. 18 - Prob. 46PCh. 18 - Prob. 47PCh. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Prob. 52DSPCh. 18 - Prob. 53DSPCh. 18 - Prob. 54DSPCh. 18 - Prob. 55DSPCh. 18 - Prob. 56DSPCh. 18 - Prob. 57DSPCh. 18 - Prob. 58DSP
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