Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Question
Chapter 12.11, Problem 12P
Interpretation Introduction
Interpretation:
The stronger base out of
Concept Introduction:
>The ability of a heteroatom like N is modified by the involvement of the lone pair in resonance.
>Resonance contributors can be drawn by moving pi electrons and lone pairs to adjacent positions.
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List the following organic bases in order of increasing basicity, starting with the least basic one and
ending with the most basic one. Please just write down the letters! Please don't use notation,
just use commas between the letters!
CH3
A
NaOH
B
CH3
C
CH3
N
D
J
Rank the following in order of increasing basicity. The first in your list should be the least basic.
HO
1
0
3 2 < 1
O2 3<1
01 2<3
01 3<2
3 1< 2
3.
2.
Consider the two following nitrophenol structures:
OH
OH
`NO2
NO2
p-nitrophenol
m-nitrophenol
Predict which will be the stronger acid. (Hint: Consider
possible resonance structures analogous to those given in
the text for phenol.)
Chapter 12 Solutions
Organic Chemistry - Standalone book
Ch. 12.2 - Write structural formulas for toluene (C6H5CH3)...Ch. 12.3 - Prob. 2PCh. 12.5 - Prob. 3PCh. 12.5 - Prob. 4PCh. 12.6 - Prob. 5PCh. 12.6 - Chrysene is an aromatic hydrocarbon found in coal...Ch. 12.8 - Prob. 7PCh. 12.9 - As measured by their first-order rate constants,...Ch. 12.9 - Give the structure of the principal organic...Ch. 12.9 - Prob. 10P
Ch. 12.10 - Prob. 11PCh. 12.11 - Prob. 12PCh. 12.12 - Prob. 13PCh. 12.13 - Prob. 14PCh. 12.13 - Prob. 15PCh. 12.15 - The regioselectivity of Birch reduction of...Ch. 12.16 - Prob. 17PCh. 12.17 - Both cyclooctatetraene and styrene have the...Ch. 12.17 - Prob. 19PCh. 12.18 - Give an explanation for each of the following...Ch. 12.19 - Prob. 21PCh. 12.19 - What does a comparison of the heats of combustion...Ch. 12.20 - Prob. 23PCh. 12.20 - Prob. 24PCh. 12.20 - Prob. 25PCh. 12.20 - Prob. 26PCh. 12.20 - Prob. 27PCh. 12.20 - Prob. 28PCh. 12.21 - Prob. 29PCh. 12.21 - Prob. 30PCh. 12.22 - Prob. 31PCh. 12.22 - Prob. 32PCh. 12 - Write structural formulas and give the IUPAC names...Ch. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - Acridine is a heterocyclic aromatic compound...Ch. 12 - Prob. 39PCh. 12 - Prob. 40PCh. 12 - Prob. 41PCh. 12 - Evaluate each of the following processes applied...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Prob. 46PCh. 12 - Anthracene undergoes a DielsAlder reaction with...Ch. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - The relative rates of reaction of ethane, toluene,...Ch. 12 - Both 1,2-dihydronaphthalene and...Ch. 12 - Prob. 52PCh. 12 - Prob. 53PCh. 12 - Prob. 54PCh. 12 - Prob. 55PCh. 12 - Prob. 56PCh. 12 - Each of the following reactions has been described...Ch. 12 - Prob. 58PCh. 12 - A compound was obtained from a natural product and...Ch. 12 - Prob. 60PCh. 12 - Suggest reagents suitable for carrying out each of...Ch. 12 - Prob. 62PCh. 12 - Prob. 63DSPCh. 12 - Prob. 64DSPCh. 12 - Prob. 65DSPCh. 12 - Prob. 66DSP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Using pKa Values to Determine Relative Acidity and Basicity Rank the following compounds in order of increasing acidity, and then rank their conjugate bases in order of increasing basicity.arrow_forward3. Rank the following primary amines (anilines in this case) in order of increasing basicity (1 = least basic, 4 = most basic). Write the conjugate acid and provide a brief explanation for your ordering. NH2 NH2 NH2 NH2 OCH3 NO2 CH3 A В C Darrow_forwardWhat is the correct rank of the following compounds in order of decreasing acidity? 16 NH2 II IV Multiple Choice IV < III < || < | |< || < ||| < IV III < || < | < IV I| < IV < |< |Il|arrow_forward
- Choose the stronger (less stable, more basic, more reactive) base in the following pair of molecules. Consider the basicity of only the indicated atom. A B ОА Barrow_forward3, Which of the molecules drawn below is most acidic? Draw the conjugate base and explain thoroughly. वे देई d a C barrow_forwardChoose the weak base from the compounds below. OCH3COOCH3 CH3SCH3 OCH3CH21 O(CH3)2NH OCH3CH3arrow_forward
- Rank the following organic molecules in order of decreasing acidity. That is, select '1' in the second column for the most acidic molecule, '2' for the next most acidic molecule, and so on. HO HO Jl. CI OH OH (Choose one) (Choose one) (Choose one) ▼ (Choose one) ▼ Xarrow_forwardWhich of the following compounds is the strongest base? O O O MeO 0₂N NH₂ -NH₂ NH₂ NH₂arrow_forwardWrite an equation for the proton transfer reaction that occurs when the following base reacts with water. Draw curved arrows that show a mechanism for the proton transfer, and modify the given structures to draw the resulting products. \ 7 11 TYZ NV + OCX D H₂C H₂C- डे H.C Di H₂C H-01H O I N O P S F LL CI Br I L 141arrow_forward
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