Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 11.9, Problem 11.19P
(a)
Interpretation Introduction
To determine: The conversion of
Interpretation: The conversion of
Concept introduction: The best reagent used for the conversion of secondary alcohol into alkyl chloride in trans to trans or cis to cis form is
(b)
Interpretation Introduction
To determine: The conversion of
Interpretation: The conversion of
Concept introduction: The best reagent used for the conversion of secondary alcohol into alkyl chloride in trans to cis form is
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What is the name for this compound?
Select one:
a.
2-bromo-5-ethylphenol
b.
4-bromo-1-ethyl-5-phenol
c.
6-bromo-3-ethylphenol
d.
2-bromo-5-ethylcyclohexanol
e.
2-bromo-5-methylphenol
Draw the structure of the following compounds.
a. 1-ethyl-3-methylcycloheptane
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2. Suggest two chemical tests that one could use to distinguish between each the following pairs of
compounds. Explain all expected observations.
a. Pentane and 1-pentene
b. 1-Pentene and 1-pentyne
C.
3-Bromo-3-methyl-1-pentene and bromobenzene
Chapter 11 Solutions
Organic Chemistry (9th Edition)
Ch. 11.1 - Prob. 11.1PCh. 11.2C - Prob. 11.2PCh. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.4PCh. 11.3 - Prob. 11.5PCh. 11.3 - Suggest the most appropriate method for each of...Ch. 11.4 - A chronic alcoholic requires a much larger dose of...Ch. 11.4 - Unlike ethylene glycol, propylene glycol...Ch. 11.5 - Predict the major products of the following...Ch. 11.5 - Show how you would convert propan-1-ol to the...
Ch. 11.6 - Predict the products of the following reactions....Ch. 11.7A - Propose a mechanism for the reaction of a....Ch. 11.7B - Prob. 11.13PCh. 11.7B - Show how you would use a simple chemical test to...Ch. 11.7C - Neopentyl alcohol, (CH3)3CCH2OH, reacts with...Ch. 11.7C - Prob. 11.16PCh. 11.7C - When cis-2-methylcyclohexanol reacts with the...Ch. 11.8 - Prob. 11.18PCh. 11.9 - Prob. 11.19PCh. 11.9 - Prob. 11.20PCh. 11.9 - Prob. 11.21PCh. 11.10A - Prob. 11.22PCh. 11.10A - Some alcohols undergo rearrangement or other...Ch. 11.10B - Prob. 11.24PCh. 11.10B - Explain why the acid-catalyzed condensation is a...Ch. 11.10B - Prob. 11.26PCh. 11.10B - When the following substituted cycloheptanol...Ch. 11.11A - Prob. 11.28PCh. 11.11A - Prob. 11.29PCh. 11.11B - Predict the products formed by periodic acid...Ch. 11.12 - Prob. 11.31PCh. 11.13A - Prob. 11.32PCh. 11.14 - Prob. 11.33PCh. 11.14 - a. Show how ethanol and cyclohexanol may be used...Ch. 11.14 - Prob. 11.35PCh. 11.14 - Phenols (pKa 10) are more acidic than other...Ch. 11.14 - To practice working through the early parts of a...Ch. 11.14 - Prob. 11.38PCh. 11 - Predict the major products of the following...Ch. 11 - Show how you would convert 2-methylcyclopentanol...Ch. 11 - In each case, show how you would synthesize the...Ch. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Both cis- and trans-2-methylcyclohexanol undergo...Ch. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Show how you would make each compound, beginning...Ch. 11 - Predict the major products (including...Ch. 11 - Show how you would use simple chemical tests to...Ch. 11 - The compound shown below has three different types...Ch. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Prob. 11.55SPCh. 11 - Show how you would synthesize the following...Ch. 11 - Show how you would synthesize the following...Ch. 11 - The following pseudo-syntheses (guaranteed not to...Ch. 11 - Two unknowns, X and Y, both having the molecular...Ch. 11 - The Williamson ether synthesis involves the...Ch. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Alcohols combine with ketones and aldehydes to...Ch. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SP
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- 5. What is the IUPAC name for the following compound? a. 4-hexanone b. 3-hexanone c. ethyl propyl ketone d. propyl ethyl ketone 6. What is the IUPAC name for the following compound? HO OH a. 2,3-dihydroxycyclopentanone b. 1,2-dihydroxy-3-cyclopentanone c. cyclopentanone-1,2-diol 7. What is the correct order of boiling points for the following compounds? ean d. cyclopentanone-2,3-diol HO. A B a. A>B>C b. C>B>A с. В> A>С d. A>C>B 8. Which of the following has the highest water solubility? a. butanal ь. 1-butanol c. I-hexanol d. hexanal 9. Which of the following is true of ketones? a. Most ketones are odorless. b. Most ketones have mild odors. c. Most ketones have strong pleasant odors. d. Most ketones have strong unpleasant odors. JPW Te orheries 10. Which of the following statements is true? a. Both aldehydes and ketones are easily oxidized. b. Neither aldehydes nor ketones are easily oxidized. c. Aldehydes are easily oxidized, but ketones are not. d. Ketones are easily oxidized, but…arrow_forwardName the following compound: H 4-chloro-4-methyl-5-oxopentanal O a. O b. 4-chloro-4-methylpentanal O c. 2-chloro-2-methylpentandial O d. 2-chloro-2-methyl-3-oxopropanalarrow_forward1. In dash-wedge-line structure, the dashes represent the: * A. bonds in the plane of the page. B. bonds away from observer. C. bonds towards observer. D. bonds in the plane of the paper. 2. Which of the following is an ACYCLIC SATURATED hydrocarbon? * A. 1-Ethyl-3-methylcyclopentane B. 3-Ethyl-3-methylpentane C. 1,3,5,7-Octatetraene D. 5-Methyl-1,3-cyclopentadiene 3. Which of the following is a CYCLIC SATURATED hydrocarbon? * A. 3-Ethyl-4-methylcyclohexene B. 3,5-Diethyloctane C. 2,2-Dimethyl-3-heptyne D. 3-Butyl-1,1-dimethyl-5-propylcyclohexanearrow_forward
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