Concept explainers
Convert each shorthand structure to a complete structure with all atoms and lone pairs drawn in.
-
a.
b.
c.
d.
(a)
Interpretation:
To convert the following shorthand structure to complete structure with all atoms and lone pairs drawn.
Concept Introduction:
Complete structure of a compound is the one in which all the bonds, atoms and lone pairs are shown. Example of complete structure is given below.
In shorthand structure, bond between the atoms and lone pairs of atoms are not shown. But, in complete structure, all the bonds between atoms and lone pairs are shown.
Answer to Problem 37P
Complete structure of the compound is,
Explanation of Solution
Given compound is as follows:
To −CH group two methyl
(b)
Interpretation:
To convert the following shorthand structure to complete structure with all atoms and lone pairs drawn.
Concept Introduction:
Complete structure of a compound is the one in which all the bonds, atoms and lone pairs are shown. Example of complete structure is given below.
In shorthand structure, bond between the atoms and lone pairs of atoms are not shown. But, in complete structure, all the bonds between atoms and lone pairs are shown.
Answer to Problem 37P
Complete structure of the compound is as follows:
Explanation of Solution
In the compound
Hence, complete structure of the compound is as follows:
(c)
Interpretation:
To convert the following shorthand structure to complete structure with all atoms and lone pairs drawn.
Concept Introduction:
Complete structure of a compound is the one in which all the bonds, atoms and lone pairs are shown. Example of complete structure is given below.
In shorthand structure, bond between the atoms and lone pairs of atoms are not shown. But, in complete structure, all the bonds between atoms and lone pairs are shown.
Answer to Problem 37P
Complete structure of the compound is as follows:
Explanation of Solution
Given compound is as follows:
In the complete structure, all the bonds between atoms and lone pairs are to be shown. Two oxygen atoms present. Both the oxygen atoms have two lone pairs (as the total number of valence electron of O is 6 and out of these 2 are involved in bond formation) on it. Hence, complete structure of the compound is as follows:
(d)
Interpretation:
To convert the following shorthand structure to complete structure with all atoms and lone pairs drawn.
Concept Introduction:
Complete structure of a compound is the one in which all the bonds, atoms and lone pairs are shown. Example of complete structure is given below.
In shorthand structure, bond between the atoms and lone pairs of atoms are not shown. But, in complete structure, all the bonds between atoms and lone pairs are shown.
Answer to Problem 37P
Complete structure is as follows:
Explanation of Solution
Given compound is as follows:
In complete structure, all the carbon atoms, hydrogen atoms and all the lone pairs should be shown. In the compound two chlorine atoms (as the total number of valence electron of Cl is 7 and out of these 1 is involved in bond formation), one oxygen atom and one −OH group(as the total number of valence electron of O is 6 and out of these 2 are involved in bond formation) present which has lone pairs. So, complete structure is as follows:
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Chapter 11 Solutions
General, Organic, and Biological Chemistry - 4th edition
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