Concept explainers
(a)
Interpretation:
The combination of halo
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(b)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(c)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(d)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(e)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(f)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(g)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(h)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(i)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(j)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(k)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
(l)
Interpretation:
The combination of halo alkane and nucleophile that will produce a give product has to be suggested.
Concept Introduction:
The rate of substitution reaction depended on both substrate and nucleophile is known as bimolecular nucleophilic substitution reaction
Trending nowThis is a popular solution!
Chapter 9 Solutions
Organic Chemistry
- Predict the major product or the necessary reagent or reactant to complete each of the following reactions. In the box before each reaction, indicate the mechanism followed by the reaction. (Free radical (FR), SN2, SN1). (b) (a) Cl₂ CH₂CH₂OH (a) 1 hv 2 (b) H Br H₂O Na+ SCH3 (c) (d) CI "CH3arrow_forwardPredict the products of reaction of pent-1-yne with the following reagents.(a) 1 equivalent of HCl (b) 2 equivalents of HCl (c) excess H2, Ni(d) H2, Pd>BaSO4, quinolinearrow_forwardThe following two sets of reactions, ((a) and (b)), show possibilities for arrow pushing in individual reaction steps. Identify which is wrong and explain why. Next, using the correct arrow pushing, label which molecule is the nucleophile and which is the electrophile. (a) (b) H3C :Cl: H3C H,c-i: – →: I-CH3 + :Cl: C-C: H3C / H3C H3C-Cl: C-CH3 H3C : H,C-Cl: H3C-CI: →: I-CH3 + :Cl: H3C :Cl: H3C C-CH3 C-CI: H3C/ H3C H3Carrow_forward
- 1. How would you prepare the following alkyl halides from the appropriate alcohols? (a) ÇI (b) Br CH3 CH3CH3 CH;CHCH,CHCH3 ČH3 2. Predict the products of the following reaction: (a) он CH3 (b) H2C CH;CH,CHCH,CHCH, Per, socl2. PBr3 ? H3Carrow_forwardReaction of this bicycloalkene with bromine in carbon tetrachloride gives a trans dibro- mide. In both (a) and (b), the bromine atoms are trans to each other. However, only one of these products is formed. CH3 CH3 CH3 Br Br CH,Cl, + Br2 or Br Br (a) (b) Which trans dibromide is formed? How do you account for the fact that it is formed to the exclusion of the other trans dibromide?arrow_forwardGive reasons for the following :(i) Ethyl iodide undergoes SN2 reaction faster than ethyl bromide.(ii) (±) 2-Butanol is optically inactive.(iii) C—X bond length in halobenzene is smaller than C—X bond length in CH3—X.arrow_forward
- Electrophilic aromatic substitution usually occurs at the 1-position of naphthalene, also called the a position. Predict themajor products of the reactions of naphthalene with the following reagents.(a) HNO3, H2SO4 (b) Br2, FeBr3 (c) CH3CH2COCl, AlCl3(d) isobutylene and HFarrow_forwardWhich of the following species is likely to be a nucleophile and which an electrophile? (a) CH3CI (b) CH3S" (c) (d) N-CH CHCHarrow_forwardGive reasons for the following: (i) p-nitrophenol is more acidic than p-methylphenol. (ii) Bond length of C—O bond in phenol is shorter than that in methanol. (iii) (CH3)3C—Br on reaction with sodium methoxide (Na+ _OCH3) gives alkene as the main product and not an ether.arrow_forward
- b) Refer to the following equation to answer Q3b (i), (ii) and (iii). CH3 H,SO, Н—с—он C-CH3 ? + H2O Но- ČH3 (i) Determine the product of the above reaction. (ii) Name the above reaction. (iii) Propose the mechanism for the above reaction.arrow_forward(a) Why is the following reaction a poor method for the synthesis of t-butyl propyl ether? (b) What would be the major product from this reaction? (c) Propose a better synthesis of r-butyl propyl ether. ÇH, does not give ÇH, CH,CH,CH,-O: *Na + CH,-C-Br > CH,-C-o-CH,CH,CH, CH, CH, t-butyl propyl ether sodium propoxide 1-butyl bromidearrow_forward5. Consider the synthesis of 2-butanone from butyne: Hg2+ CH3CH,-C=C–H CH3CH, Ĉ -CH3 H3o* (i) Draw the structure of the compound D. (ii) Compound D isomerizes to form 2-butanone. What is this isomeric process called? (iii) Use the mechanism to show the conversion of compound D to 2-butanone.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY