Concept explainers
Solid calcium carbide
l type='a'>
(a)
Interpretation:
The balanced chemical reaction for the solid calcium carbide with liquid water should be determined.
Concept Introduction:
A balanced chemical equation is an equation that contains same number of atoms as well as of each element of reactants and products of reaction.
For example, the reaction between lead sulphide and oxygen is as follows:
Mass of any substance can be calculated as follows:
Number of moles can be calculated as follows;
Answer to Problem 20CR
The balance equation for the solid calcium carbide with liquid water is as follows:
Explanation of Solution
The limiting reactant in a particular reaction has due to following properties:
- Limiting reactant completely reacted in a particular reaction.
- Limiting reactant determines the amount of the product in mole.
If any reactant left after competitions of reaction, thus it is said to excess reactant.
The balance equation for the solid calcium carbide with liquid water is as follows:
(b)
Interpretation:
The limiting reagent should be determined.
Concept Introduction:
A balanced chemical equation is an equation that contains same number of atoms as well as of each element of reactants and products of reaction.
For example, the reaction between lead sulphide and oxygen is as follows:
Mass of any substance can be calculated as follows:
Number of moles can be calculated as follows;
Answer to Problem 20CR
Explanation of Solution
The limiting reactant in a particular reaction has due to following properties:
- Limiting reactant completely reacted in a particular reaction.
- Limiting reactant determines the amount of the product in mole.
If any reactant left after competitions of reaction, thus it is said to excess reactant.
The balance equation for the solid calcium carbide with liquid water is as follows:
Given:
Amount of
Amount of
Calculation:
Number of moles of
Amount of other reactant is calculated as follows:
Here, water is a limiting agent and calcium carbide present in excess.
(c)
Interpretation:
To prove that mass in conserved for reactant
Concept Introduction:
A balanced chemical equation is an equation that contains same number of atoms as well as of each element of reactants and products of reaction.
For example, the reaction between lead sulphide and oxygen is as follows:
Mass of any substance can be calculated as follows:
Number of moles can be calculated as follows;
Answer to Problem 20CR
Both sides amount approximately equal thus that mass in conserved for reactant.
Explanation of Solution
The limiting reactant in a particular reaction has due to following properties:
- Limiting reactant completely reacted in a particular reaction.
- Limiting reactant determines the amount of the product in mole.
If any reactant left after competitions of reaction, thus it is said to excess reactant.
The balance equation for the solid calcium carbide with liquid water is as follows:
Given:
Amount of
Amount of
Calculation:
Number of moles of
Amount of other reactant which left after reaction is calculated as follows:
Amount of product in gram calculated as follows:
Now;
Amount of reaming reactant + total product amount = amount of used reactants
Both sides amount approximately equal thus that mass in conserved for reactant.
Want to see more full solutions like this?
Chapter 9 Solutions
Introductory Chemistry: A Foundation
- Carbon dioxide from the atmosphere weathers, or dissolves, limestone (CaCO3) by the reaction CaCO3(s)+CO2(g)+H2O(l)Ca2(aq)+2HCO3(aq) Obtain H for this reaction. See Table 6.2 for the data.arrow_forwardA power plant is driven by the combustion of a complex fossil fuel having the formula C11H7S. Assume the air supply is composed of only N2 and O2 with a molar ratio of 3.76:1.00, and the N2 remains unreacted. In addition to the water produced, the fuels C is completely combusted to CO2 and its sulfur content is converted to SO2. In order to evaluate gases emitted at the exhaust stacks for environmental regulation purposes, the nitrogen supplied with the air must also be included in the balanced reactions. a Including the N2 supplied m the air, write a balanced combustion equation for the complex fuel assuming 100% stoichiometric combustion (i.e., when there is no excess oxygen in the products and the only C-containing product is CO2). Except in the case of N2, use only integer coefficients. b Including N2 supplied in the air, write a balanced combustion equation for the complex fuel assuming 120% stoichiometric combustion (i.e., when excess oxygen is present in the products and the only C-containing product is CO2). Except in the case of use only integer coefficients c Calculate the minimum mass (in kg) of air required to completely combust 1700 kg of C11H7S. d Calculate the air/fuel mass ratio, assuming 100% stoichiometric combustion. e Calculate the air/fuel mass ratio, assuming 120% stoichiometric combustion.arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forward
- When one mole of ethylene gas, C2H4, reacts with fluorine gas, hydrogen fluoride and carbon tetrafluoride gases are formed and 2496.7 kJ of heat are given off. What is Hf for CF4(g)?arrow_forwardOn Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?arrow_forwardA rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forward
- Insoluble AgCl(s) precipitates when solutions of AgNO3(aq) and NaCl(aq) are mixed. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) rH = ? To measure the energy evolved in this reaction, 250. mL of 0.16 M AgNO3(aq) and 125 mL of 0.32 M NaCl(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises from 21.15 C to 22.90 C. Calculate the enthalpy change for the precipitation of AgCl(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL and its specific heat capacity is 4.2 J/g K.)arrow_forwardMany cereals are made with high moisture content so that the cereal can be formed into various shapes before it is dried. A cereal product containing 58% H2O by mass is produced at the rate of 1000. kg/h. What mass of water must be evaporated per hour if the final product contains only 20.% water?arrow_forwardWrite a balanced equation for the reaction between (a) dihydrogen sulfide and sulfur dioxide gases to form sulfur solid and steam. (b) methane, ammonia, and oxygen gases to form hydrogen cyanide gas and steam. (c) iron(lll) oxide and hydrogen gas to form molten iron and steam. (d) uranium(IV) oxide and hydrogen fluoride gas to form uranium(IV) fluoride and steam. (e) the combustion of ethyl alcohol (C2H5OH) to give carbon dioxide and water.arrow_forward
- What is Hrxn for reaction of iron(III) oxide and carbon monoxide to give iron metal and carbon dioxide gas? Use the following reactions: 4Fe(s)+3O2(g)2Fe2O3(s)H=1648.4kJ4CO(g)+O2(g)2CO3(g)H=565.98kJarrow_forwardlist at least three quantities that must be conserved in chemical reactions.arrow_forward
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning