From the given molecules, more reactive alkyl halide has to be identified. Concept Introduction: The S N 2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S N 2 is a kind of nucleophilic substitution reaction mechanism. Steric effect is the effect due to the groups occupies a certain volume of space. Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

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Answer 1

Question

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

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Explain the observed rate of reactivity of the following 2° alkyl halides in an SN1 reaction.

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Answer 2

Question

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

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Answer 3

Question

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

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Answer 4

Question

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

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Answer 5

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 6

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 7

Chapter 8.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 8

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

Answer 9

(b)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Leaving propensity depends on the basicity because weak base are stable bases; the readily bear the electrons. Thus they do not share the electrons.

Answer 10

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide is to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 13

(d)

Interpretation Introduction

Interpretation:

From the given molecules, more reactive alkyl halide has to be identified.

Concept Introduction:

The S_N2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. S_N2 is a kind of nucleophilic substitution reaction mechanism.

Steric effect is the effect due to the groups occupies a certain volume of space.

Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.1 - Prob. 2P Ch. 8.1 - Does increasing the energy barrier for an SN2...Ch. 8.1 - Arrange the following alkyl bromides in order from...Ch. 8.2 - Prob. 7P Ch. 8.2 - Which reaction in each of the following pairs...Ch. 8.2 - Prob. 9P Ch. 8.2 - Prob. 11P Ch. 8.3 - Draw the substitution products that will be formed...Ch. 8.4 - Arrange the following alkyl halides in order from...Ch. 8.5 - Prob. 14P

Solution Summary: The author explains that the S N 2 reaction is a kind of nucleophilic substitution reaction mechanism.

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