Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 8, Problem 88QAP
A sample of sucrose, C12H22O11, is contaminated by sodium chloride. When the contaminated sample is burned in a bomb calorimeter, sodium chloride does not burn. What is the percentage of sucrose in the sample if a temperature increase of 1.67°C is observed when 3.000 g of the sample are burned in the calorimeter? Sucrose gives off
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Chapter 8 Solutions
Chemistry: Principles and Reactions
Ch. 8 - Principles of Heat Flow Titanium is a metal used...Ch. 8 - Prob. 2QAPCh. 8 - Copper is used in building the integrated...Ch. 8 - Mercury was once used in thermometers and...Ch. 8 - The specific heat of aluminum is 0.902J/gC. How...Ch. 8 - Chromium has a specific heat of 0.450J/gC. How...Ch. 8 - Magnesium sulfate is often used in first-aid hot...Ch. 8 - Sodium chloride is added in cooking to enhance the...Ch. 8 - When 375 mL of water (d=1.00g/mL) at 32C are mixed...Ch. 8 - How many mL of water at 10C (2 significant...
Ch. 8 - When one mol of KOH is neutralized by sulfuric...Ch. 8 - The heat of neutralization, Hneut, can be defined...Ch. 8 - Fructose is a sugar commonly found in fruit. A...Ch. 8 - In earlier times, ethyl ether was commonly used as...Ch. 8 - Isooctane is a primary component of gasoline and...Ch. 8 - Ethyl alcohol, C2H5OH, is the intoxicating agent...Ch. 8 - Acetic acid, HC2H3O2, is responsible for the sour...Ch. 8 - Acetylene, C2H2, is used in welding torches. It...Ch. 8 - Salicylic acid, C7H6O3, is one of the starting...Ch. 8 - Methanol (CH3OH) is also known as wood alcohol and...Ch. 8 - Nitrogen oxide (NO) has been found to be a key...Ch. 8 - Small amounts of oxygen gas can be prepared in the...Ch. 8 - In the late eighteenth century Priestley prepared...Ch. 8 - Prob. 24QAPCh. 8 - Strontium metal is responsible for the red color...Ch. 8 - Nitroglycerin, C3H5(NO3)3(l), is an explosive most...Ch. 8 - A typical fat in the body is glyceryl trioleate,...Ch. 8 - Use the same fat described in Question 27. (a)...Ch. 8 - Which requires the absorption of a greater amount...Ch. 8 - Which evolves more heat—freezing 100.0 g of...Ch. 8 - A student is asked to calculate the amount of heat...Ch. 8 - Follow the step-wise process outlined in Problem...Ch. 8 - A lead ore, galena, consisting mainly of lead(II)...Ch. 8 - A reaction used to produce the silicon for...Ch. 8 - Given the following thermochemical equations,...Ch. 8 - Given the following thermochemical equations:...Ch. 8 - Write thermochemical equations for the...Ch. 8 - Write thermochemical equations for the formation...Ch. 8 - Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is...Ch. 8 - Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What...Ch. 8 - Limestone, CaCO3, when subjected to a temperature...Ch. 8 - When hydrazine reacts with oxygen, nitrogen gas...Ch. 8 - Use Table 8.3 to obtain AHO for the following...Ch. 8 - Use Table 8.3 to obtain H for the following...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - When one mole of nitroglycerine, C3H5(NO3)3(l)...Ch. 8 - When one mole of calcium carbonate reacts with...Ch. 8 - Chlorine trifluoride is a toxic, intensely...Ch. 8 - When one mole of ethylene gas, C2H4, reacts with...Ch. 8 - Glucose, C6H12O6(s), (H f =1275.2kJ/mol) is...Ch. 8 - When ammonia reacts with dinitrogen oxide gas (H f...Ch. 8 - How many kJ are equal to 3.27 L atm of work?Ch. 8 - How many L atm are equal to 12.2 kJ of work?Ch. 8 - Find (a) E when a gas absorbs 18 J of heat and has...Ch. 8 - Calculate (a) q when a system does 54 J of work...Ch. 8 - Consider the following reaction in a vessel with a...Ch. 8 - Consider the following reaction in the vessel...Ch. 8 - Determine the difference between H and E at 25C...Ch. 8 - For the vaporization of one mole of bromine at...Ch. 8 - Consider the combustion of propane, C3H8, the fuel...Ch. 8 - Consider the combustion of one mole of methyl...Ch. 8 - Butane gas, C4H10, is sold to campers as bottled...Ch. 8 - The BTU (British thermal unit) is the unit of...Ch. 8 - Natural gas companies in the United States use the...Ch. 8 - Prob. 66QAPCh. 8 - Given the following reactions,...Ch. 8 - In World War II, the Germans made use of otherwise...Ch. 8 - Prob. 69QAPCh. 8 - Consider the reaction between methane and oxygen...Ch. 8 - Consider burning ethane gas, C2H6 in oxygen...Ch. 8 - On complete combustion at constant pressure, a...Ch. 8 - Microwave ovens convert radiation to energy. A...Ch. 8 - In 2010, 3.30109 gallons of gasoline were consumed...Ch. 8 - Some solar-heated homes use large beds of rocks to...Ch. 8 - Consider a solution prepared by dissolving 10.00 g...Ch. 8 - Draw a cylinder with a movable piston containing...Ch. 8 - Redraw the cylinder in Question 77 after work has...Ch. 8 - Which statement(s) is/are true about bond...Ch. 8 - Equal masses of liquid A, initially at 100C, and...Ch. 8 - Determine whether the statements given below are...Ch. 8 - An exothermic reaction is carried out in a...Ch. 8 - Determine whether the statements given below are...Ch. 8 - Microwave ovens emit microwave radiation that is...Ch. 8 - On a hot day, you take a six-pack ot a on a pcmc,...Ch. 8 - Prob. 86QAPCh. 8 - The thermite reaction was once used to weld rails:...Ch. 8 - A sample of sucrose, C12H22O11, is contaminated by...Ch. 8 - A wad of steel wool (specific heat=0.45J/gC) at...Ch. 8 - Consider a metal ion A2+ and its nitrate salt, In...
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- Hypothetical elements A2 and B2 react according to the following equation, forming the compound AB. A2(aq)+B2(aq)2AB(aq);H=+271kJ/mol If solutions A2(aq) and B2(aq), starting at the same temperature, are mixed in a coffee-cup calorimeter, the reaction that occurs is a exothermic, and the temperature of the resulting solution rises. b endothermic, and the temperature of the resulting solution rises. c endothermic, and the temperature of the resulting solution falls. d exothermic, and the temperature of the resulting solution falls. e exothermic or endothermic, depending on the original and final temperatures.arrow_forwardAcetic acid, HC2H3O2, is the sour constituent of vinegar (acetum is Latin for vinegar). In an experiment, 3.58 g of acetic acid was burned. HC2H3O2(l)+2O2(g)2CO2(g)+2H2O(l) If 52.0 kJ of heat evolved, what is H per mole of acetic acid?arrow_forwardIn a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each experiment. Since the amount of water is not constant from experiment to experiment, the mass of water must be measured in each case. The heat capacity of the calorimeter is broken down into two parts: the water and the calorimeter components. If a calorimeter contains 1.00 kg water and has a total heat capacity of 10.84 kJ/C, what is the heat capacity of the calorimeter components?arrow_forward
- Insoluble PbBr2(s) precipitates when solutions of Pb(NO3)2(aq) and NaBr(aq) are mixed. Pb(NO3)2(aq) + 2 NaBr(aq) PbBr2(s) + 2 NaNO3(aq) rH = ? To measure the enthalpy change, 200. mL. of 0.75 M Pb(NO3)2(aq) and 200. mL of 1.5 M NaBr(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises by 2.44 C. Calculate the enthalpy change for the precipitation of PbBr2(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL., and its specific heat capacity is 4.2 J/g K.)arrow_forwardThe standard enthalpy of formation of solid barium oxide, BaO, is 553.5 kJ/mol, and the standard enthalpy of formation of barium peroxide, BaO2, is 634.3 kJ/mol. (a) Calculate the standard enthalpy change for the following reaction. Is the reaction exothermic or endothermic? 2 BaO2(s) 2 BaO(s) + O2(g) (b) Draw an energy level diagram that shows the relationship between the enthalpy change of the decomposition of BaO2, to BaO and O2, and the enthalpies of formation of BaO2(s) and BaO2(s).arrow_forwardNitrogen monoxide, a gas recently found to be involved in a wide range of biological processes, reacts with oxygen to give brown NO2 gas. 2 NO(g) + O2(g) NO2(g)rH = 114.1 kJ/mol-rxn Is this reaction endothermic or exothermic? What is the enthalpy change if 1.25 g of NO is converted completely to NO2?arrow_forward
- Formic acid, HCHO2, was first discovered in ants (formica is Latin for ant). In an experiment, 5.48 g of formic add was burned at constant pressure. 2HCHO2(l)+O2(g)2CO2(g)+2H2O(l) If 30.3 kJ of heat evolved, what is H per mole of formic acid?arrow_forwardThe enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.arrow_forwardA 0.470-g sample of magnesium reacts with 200 g dilute HCl in a coffee-cup calorimeter to form MgCl2(aq) and H2(g). The temperature increases by 10.9 C as the magnesium reacts. Assume that the mixture has the same specific heat as water and a mass of 200 g. (a) Calculate the enthalpy change for the reaction. Is the process exothermic or endothermic? (b) Write the chemical equation and evaluate H.arrow_forward
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