Concept explainers
(a)
To determine: The products of the reaction of
Interpretation: The products of the reaction of
Concept introduction: The
According to the Zaitsev rule, the formation of
(b)
To determine: The products of the reaction of
Interpretation: The products of the reaction of
Concept introduction: The
According to the Zaitsev rule, the formation of alkene occurs by the elimination of the hydrogen from the carbon that has less number of hydrogen.
(c)
To determine: The products of the reaction of
Interpretation: The products of the reaction of
Concept introduction: The
According to the Zaitsev rule, the formation of alkene occurs by the elimination of the hydrogen from the carbon that has less number of hydrogen.
(d)
To determine: The products and the type of reactions occur between the given compounds.
Interpretation: The products and the type of reactions that occur between the given compounds are to be stated.
Concept introduction: In
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Organic Chemistry (9th Edition)
- Give IUPAC names to the following molecules. CI a. b. b. b. C. d. Br CI- Draw all the products (alkyl halides) of the following reactions and classify them as primary, secondary, or tertiary a. OH X . Br Br Complete the following reactions by filling in the missing reagents. a. OH NBS hv OH hv, CC14 Br NBS ť Licu C. -MgBr CI → CI Br Brarrow_forward1) Give the major organic product of the following reaction. Don't forget stereochemistry in certain cases. 2) Assign the reaction as addition, elimination, substitution, or rearrangement. A. B. C. D. xx D D 1. H₂O/Hg(OAc)2 2. NaBH₂ Br₂ CCI (inert solvent) H₂/Pd/C HBr Type of Reaction: Type of Reaction: Type of Reaction: Type of Reaction:arrow_forward1. 2-bromobutane + cyclohexanol + NaH à (major product) c. 2-butoxycyclohexane a.. 2-butene reaction b. 1-butene d. no e. something else! 2. t-butylbromide + sodium ethoxide in ethanol à (major product) a. 2-methylpropene reaction b. t-butyl ethyl ether c. 1-methylbutene d. no e. something else! 3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room temperature à (major product) a. 1-butene reaction c. 2-methylpropene d. no b. butyl t-butyl ether e. something else! 4. t-butyl bromide + boiling hot water à (major product) a. 2-methylpropene reaction b. t-butyl ethyl ether c. t-butanol d. no e. something else! 5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major product) c. b. d. no reaction e. something а. HO. else! Br KOH / DMSO 6. b. 2-methyl-1-propanol d. 1,2- a. 2-methylpropene propanediene c. no reaction e. something else! 7. cyclopentanol+ NaH + DMSO + bromopropane à(major product) a. cyclopentene reaction b. propene e. something else!! c. propyl cyclopentyl…arrow_forward
- 6. Provide the structure for the major product in the following reactions. b. P f. OH g. Lia * Oia ملی CI 1. SOCI₂, pyr. 2. to Br 2 1. LIAIH4 (xs) 2. H₂O 1. LIAI(OR) 3H 2. H₂O 2. NH₂ Et₂CuLi 1. EtMgBr (xs) 2. H₂O 1. Mg 2. CO₂ 3. H* 4. SOCI₂, pyr 1. [H], NaBH3CN, EtNH₂ CI pyridinearrow_forwardDraw the products obtained from the SN2 reaction of a. 2-bromobutane and methoxide ion. b. (R)-2-bromobutane and methoxide ion. c. (S)-3-chlorohexane and hydroxide ion. d. 3-iodopentane and hydroxide ion.arrow_forwardA. OsO4 and NMO B. Br2 and H20 C. Hg(OAc)2, H2O and NaBH4, NaOH D. RCO3H E. BH3-THF and H2O2, NaOH Which reagent will complete this reaction?arrow_forward
- Match the reactions with their products below. HAI(OIBU)3 1. a.) CI 1.) NABH4 2. b.) H. 2.) H3O* 3. (CH3),CuLi c.) OH 4. CH3OH d.) EtgN 5. HN(CH3)2 e.) EtgNarrow_forwardWhich reagent is appropriate for the following reaction. Cyclohexene converted to trans-cyclohexane diol. A. KMNO4, cold, neutral B. 1. OsO4/2. NaHSO3, H2O С. 1. RCOOОН/2. ОН- D. HIO4arrow_forward3. Propose a reasonable mechanism for the following cyclization reactions. Then classify the cyclization and identify if the product would be favored or disfavored based on Baldwin's Rules. O a. b. C. НО. Br Ph Ph OCH 3 OH nBuLi NaOH H₂O عليم H₂SO4 1arrow_forward
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