(a)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(b)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(c)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(d)
To determine: The stronger nucleophile among the given pairs of nucleophiles used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(e)
To determine: The stronger nucleophile among the given pairs of nucleophiles used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(f)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(g)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(h)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
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Chapter 6 Solutions
Organic Chemistry (9th Edition)
- Which species is likely to undergo a reaction with the nucleophile readily? A. (ch3)3cl b. (Ch3)2HCI c. Ch3ch2cl d. CH3CIarrow_forward3. Circle the nucleophile in each pair that undergoes SN2 reaction most rapidly with Ph-CH2-Cl in acetonitrile solvent. NaOH vs NaOẠc Li-NH2 vs NH3 NaOH vs H-OHarrow_forwardSelect the product of the reaction sequence below. A. B. Br OA OB OC Br HNO3 H₂SO4 NO₂ NO₂ Br₂ FeBr3 C. D. Br H₂ Pd/C Br NH₂ NH₂arrow_forward
- An SN2 mechanism takes place when 3-(bromomethyl)pentane is added to each nucleophile listed below. Which nucleophile will also require an acid-base step after the substitution step in order to produce a neutral (not charged) product? A. LiN(CH3)2 B. NaI C. KN3 D. HSCH3 (Please type answer no write by hend)arrow_forwardWhich structure is the best nucleophile for an SN2 reaction? A. NH3 B. NH2 C. NH4* D. HCN O B O A O C None of the species shown is a suitable nucleophile for SN2.arrow_forwardIdentify the stronger nucleophile in each pair. a. NH3,−NH2 b. CH3NH2, CH3OH c. CH3CO2−, CH3CH2O−arrow_forward
- Benzyl chloride is reacted with different nucleophiles (HO-, CH3COO-, PhO-, CH3O-). Arrange them in the decreasing order of reactivity with benzyl chloride. A. CH3O¯> HO- > PhO-> CH3CO0- B. HO->CH3O-> PhO> CH3CO0- C. HO-> PhO- > CH3O¯> CH3C- D. CH3COO-> CH³O¯> HO-> PhO- Note: benzyl chloride PhO, phenoxidearrow_forwardDetermine the mechanism of nucleophilic substitution of each reaction and draw the products, including stereochemistry. CH₂CH3 a. b. C. x Br + CN Br H Br + OCH3 + CH3OH CH₂CH₂CH3 acetone DMSO d. CI + CH3 e. f. H Br CH3COOH + -OCH₂CH3 + CH3CH₂OH DMFarrow_forwardIdentify the stronger nucleophile in each pair. a.NH3, −NH2 b.CH3NH2, CH3OH c.CH3CO2−, CH3CH2O−arrow_forward
- Q#5 Show the reaction mechanism AND draw the constitutional isomer formed in each reaction. HCI a. H2O b. H2SO4 [1] BH3 С. [2] H2O2, HO- Br2 d. H2O H20 H2SO4 е. e.arrow_forwardRank the nucleophiles in each group in order of increasing nucleophilicity.a. -OH, -NH2, H2Ob. -OH, Br-, F- (polar aprotic solvent)c. H2O, -OH, CH3CO2-arrow_forward6. Draw the major neutral product of each reaction and indicate whether the predominant mechanism is S1 or S2 in each case. A. B. C. D. E. Br Br CI HO NaSMe DMF NaN3 DMF IOH OH KCN THFarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning