(a) Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated. Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R , S notations. Diastereomers are the stereoisomers that have the opposite R , S notations for at least one stereogenic center and the same R , S notations for at least one stereogenic center. Identical compounds have same R , S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R , S ). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 1

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Please identify the relationship between each pair of structures as: (i) identical, (ii) constitutional, (iii) conformational, (iv) enantiomers, or (v) diastereomers. Choose only one label per pair of structures.

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State how each pair of compounds is related. Are they enantiomers, diastereomers, constitutional isomers, or identical?

Answer 2

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 3

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 4

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 5

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 6

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 7

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 8

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 9

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 10

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 11

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 12

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 13

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 14

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Answer 17

Ch. 5.1 - Prob. 1P Ch. 5.2 - Prob. 2P Ch. 5.3 - Draw the mirror image of each compound. Label each...Ch. 5.3 - Prob. 4P Ch. 5.3 - A molecule is achiral if it has a plane of...Ch. 5.6 - Prob. 17P Ch. 5.6 - Prob. 18P Ch. 5.7 - Prob. 19P Ch. 5.7 - Prob. 20P Ch. 5.7 - Problem 5.18 Compounds E and F are two isomers of...

Solution Summary: The author explains the relation between given pair of compounds as enantiomers, diastereomer, constitutional isomeric, or identical.

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