Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 3.4, Problem 17P

(a)

Interpretation Introduction

Interpretation:

The given compounds represent the same or a different compound has to be identified.

Concept Introduction:

Isomers: Compounds that have same molecular formula but different structural formula.

Constitutional isomers: Compounds that have same molecular formula but different connectivity (arrangement of atoms are different).

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

  • The longer number of Carbon chain of a compound is identified this is called parent of the compound.
  • In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.
  • The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.
  • The names of all substituents are arranged by alphabets to starts with lowest numbering.
  • The complex substituent is built by a substituent on a substituent; so called complex substituent.
  • In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The given compounds represent the same or a different compound has to be identified.

Concept Introduction:

Isomers: Compounds that have same molecular formula but different structural formula.

Constitutional isomers: Compounds that have same molecular formula but different connectivity (arrangement of atoms are different).

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

  • The longer number of Carbon chain of a compound is identified this is called parent of the compound.
  • In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.
  • The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.
  • The names of all substituents are arranged by alphabets to starts with lowest numbering.
  • The complex substituent is built by a substituent on a substituent; so called complex substituent.
  • In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Chapter 3 Solutions

Essential Organic Chemistry (3rd Edition)

Ch. 3.3 - Draw a condensed and a skeletal structure for the...Ch. 3.3 - What is each compounds systematic name?Ch. 3.4 - Prob. 17PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.5 - Are the following compounds primary, secondary, or...Ch. 3.5 - Name the following amines and tell whether they...Ch. 3.5 - Draw the structures and provide systematic names...Ch. 3.6 - Predict the approximate size of the following bond...Ch. 3.7 - What is the smallest straight-chain alkane that is...Ch. 3.7 - Prob. 24PCh. 3.7 - Prob. 25PCh. 3.7 - Prob. 26PCh. 3.7 - List the compounds in each set from highest...Ch. 3.8 - Rank the following compounds in each set from most...Ch. 3.8 - In which solvent would cyclohexane have the lowest...Ch. 3.8 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - a. Draw the three staggered conformations and the...Ch. 3.9 - a. Draw the most stable conformation of pentane...Ch. 3.11 - Draw 1,2,3,4,5,6-hexachlorocyclohexane with a. all...Ch. 3.12 - At any one time, would you expect there to be more...Ch. 3.13 - Prob. 36PCh. 3 - a. How many hydrogens does an alkane with 17...Ch. 3 - Prob. 2PCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Name the following amines and tell whether they...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - What is each compounds name? a. CH3CH2CH2OCH2CH3Ch. 3 - Draw the structural formula for an alkane that has...Ch. 3 - Which has a. the higher boiling point:...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 51PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - Prob. 53PCh. 3 - For rotation about the C-3 8 C-4 bond of...Ch. 3 - Prob. 55PCh. 3 - What is each compounds systematic name?Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Draw the nine constitutional isomers with...Ch. 3 - Prob. 59PCh. 3 - Prob. 60PCh. 3 - Prob. 61PCh. 3 - Using Newman projections, draw the most stable...Ch. 3 - For each of the following disubstituted...Ch. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - What is each compounds systematic name?Ch. 3 - Prob. 67PCh. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - a. Draw a potential energy diagram for rotation...
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