EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 3.10, Problem 13LTS
Interpretation Introduction
Interpretation: The Lewis acid and Lewis base must be identified in the reaction between
Concept Introduction: The acidity and basicity are defined in terms of electrons by Lewis. A chemical entity that accepts the pair of electrons is said to be Lewis acid whereas the chemical entity that donates pair of electrons is said to be Lewis base.
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Chapter 3 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 3.2 - Prob. 1LTSCh. 3.2 - Prob. 1PTSCh. 3.3 - Prob. 2LTSCh. 3.3 - Prob. 4PTSCh. 3.3 - Prob. 5ATSCh. 3.3 - Prob. 6ATSCh. 3.3 - Prob. 3LTSCh. 3.3 - Prob. 7PTSCh. 3.4 - Prob. 5LTSCh. 3.4 - Prob. 13PTS
Ch. 3.4 - Prob. 6LTSCh. 3.4 - Prob. 15PTSCh. 3.4 - Prob. 16ATSCh. 3.4 - Prob. 17ATSCh. 3.4 - Prob. 7LTSCh. 3.4 - Prob. 18PTSCh. 3.4 - Prob. 19PTSCh. 3.4 - Prob. 8LTSCh. 3.4 - Prob. 23PTSCh. 3.4 - Prob. 24PTSCh. 3.4 - Prob. 25ATSCh. 3.4 - Prob. 26ATSCh. 3.10 - Prob. 13LTSCh. 3 - Prob. 37PPCh. 3 - Prob. 38PPCh. 3 - Prob. 39PPCh. 3 - Prob. 40PPCh. 3 - Prob. 41PPCh. 3 - Prob. 42PPCh. 3 - Prob. 44PPCh. 3 - Prob. 45PPCh. 3 - Prob. 46PPCh. 3 - Prob. 47PPCh. 3 - Prob. 48PPCh. 3 - Prob. 49PPCh. 3 - Prob. 50PPCh. 3 - Prob. 51PPCh. 3 - Prob. 52PPCh. 3 - Prob. 64IPCh. 3 - Prob. 66IPCh. 3 - Prob. 67IPCh. 3 - Prob. 71IPCh. 3 - Prob. 72IPCh. 3 - Prob. 73IPCh. 3 - Prob. 74IPCh. 3 - Prob. 75IPCh. 3 - Prob. 76IP
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- The hydrogen phthalate ion, C8HsO4, is a weak acid with Ka = 3.91 106. C8H5O4(aq)+H2O(l)C8H4O42(aq)+H3O+(aq) What is the pH of a 0.050 M solution of potassium hydrogen phthalate. KC8H5O4? Note: To find the pH for a solution of the anion, we must take into account that the ion is amphiprotic. It can be shown that, for most cases of amphiprotic ions, the H3O+ concentration is [H3O+]=Ka1Ka2 For phthalic acid, C8H6O4 is Ka1 is 1.12 103, and Ka2 is 3.91 106.arrow_forwardFor conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)arrow_forwardThe formula for tartaric acid is preferably written as H2C4H4O6 rather than as C4H6O6. Explain why.arrow_forward
- Follow the directions of Question 19 for the following acids: (a) hypochlorous acid (b) formic acid, HCHO2 (c) acetic acid, HC2H3O2 (d) hydrobromic acid (e) sulfurous acidarrow_forwardWhat is the equilibrium constant expression (Ka) for the acid dissociation of hypochlorous acid? HClO(aq)+H 2 O(l) H 3 O^ + (aq)+ClO-(aq) . a) Ka=[H 3 O^ + ]+[ClO-]-[HClO]; b) Ka=([HClOl[H 2 O]/([H 3 O^ + ][ClO-]); c) Ka=([H 3 O^ + ][ClO-])/([HClO][H 2 O]; d) Ka=(IH 3 O^ + ][ClO-])/[HClO]arrow_forwardWhich one of the following salts, when added to water, would decrease the pH? O CSCN O LICH3COO O KHSO4 O Ba(CIO₂2) 2 NaBrOarrow_forward
- Why does boric acid function as such a very weak monobasic acid?arrow_forwardCalculate the concentration carbon dioxide in water and pH of water at 25 degree Celsius and at 1 atm saturated with air with 0.0410 % by volume of CO2arrow_forwardComplete the balanced molecular reaction for the following weak acid with a strong base: HC2H3O2(aq) + NaOH(aq) ->arrow_forward
- What is the pH of 8.1 x 105 M HCIO4 solution? Is it acidic, basic or neutral? 4.09; acidic O 4.09; basic O -4.09; neutral O 9.91; basicarrow_forwardRank the acid strength of HClO, HClO2, and HBrO from weakest to strongest.arrow_forwardWhat is the pH of a substance with a hydrogen concentration of 3.0 x 10-12?arrow_forward
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General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY