Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 28.11, Problem 10P
Interpretation Introduction
Interpretation: A lactam has to be explained. The structure of
Concept introduction:
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a) Write and name of the mechanlam when chloroethane is refluxed with ethenolic
polassium cyanide.
MeO
22.55 One potential synthesis of the anti-inflammatory and analgesic drug nabumetone
is chloromethylation (Problem 22.48) of 2-methoxynaphthalene followed by an
acetoacetic ester synthesis (Section 19.6).
5
3
6
CH₂O
CI
acetoacetic
ester
synthesis
HC
7
MeO
MeO
1
8
2-Methoxynaphthalene
Nabumetone
(a) Account for the regioselectivity of chloromethylation at carbon 6 rather than at
carbon 5 or 7.
(b) Show steps in the acetoacetic ester synthesis by which the synthesis of nabum-
etone is completed.
19 & 20.
19.
20.
Consider the following synthetic estrogen shown below
O=
H
Im
Compound X
The maximum number of stereoisomers in X is
Illllllll
CH3
a
OH
CH3
Draw compound X below and prioritize the groups present in the stereocenter labeled as a.
Chapter 28 Solutions
Organic Chemistry - Standalone book
Ch. 28.2 - Prob. 1PCh. 28.3 - Prob. 2PCh. 28.3 - Prob. 3PCh. 28.4 - Prob. 4PCh. 28.7 - Problem 28.5 (a) Write a chemical equation for the...Ch. 28.7 - Prob. 6PCh. 28.8 - Prob. 7PCh. 28.9 - Problem 28.8 How will the average chain length of...Ch. 28.9 - Prob. 9PCh. 28.11 - Prob. 10P
Ch. 28.11 - Prob. 11PCh. 28.12 - Prob. 12PCh. 28.13 - Prob. 13PCh. 28.14 - Prob. 14PCh. 28 - Prob. 15PCh. 28 - Prob. 16PCh. 28 - Prob. 17PCh. 28 - Prob. 18PCh. 28 - Prob. 19PCh. 28 - Prob. 20PCh. 28 - Of the following monomers, which one would undergo...Ch. 28 - Prob. 22PCh. 28 - Polymerization of styrene can occur by a...Ch. 28 - Styrene undergoes anionic polymerization at a...Ch. 28 - Prob. 25PCh. 28 - Prob. 26PCh. 28 - Prob. 27PCh. 28 - Prob. 28PCh. 28 - Prob. 29PCh. 28 - Prob. 30PCh. 28 - Prob. 31PCh. 28 - Prob. 32DSPCh. 28 - Prob. 33DSPCh. 28 - Prob. 34DSPCh. 28 - Prob. 35DSPCh. 28 - Prob. 36DSPCh. 28 - Prob. 37DSPCh. 28 - Prob. 38DSP
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