EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 2.5, Problem 4LTS
Interpretation Introduction
Interpretation: The lone pairs associated with the nitrogen atoms in the given compound should be drawn.
Concept Introduction: The unshared pair of electrons are said to be lone pairs of electrons that are present in an atom of a compound.
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Unshared, or lone, electron pairs play an important role in determining the chermical and physical properties of organic compounds. Thus, it is important
to know which atoms carry unshared pairs.
Use the structural formulas below to determine the number of unshared pairs at each designated atom.
Be sure your answers are consistent with the formal charges on the formulas.
The number of unshared pairs at atom a is
The number of unshared pairs at atom b is
HyC
CH
The number of unshared pairs at atom e is
The number of unshared pairs at atom a is
The number of unshared pairs at atom b is
HC
CH
The number of unshared pairs at atom e is
Predict the indicated bond angles in each compound drawn as a Lewis structure with no implied geometry.
Determine the number of lone pairs (if any) on each oxygen, nitrogen and charged carbon atoms in the following structures.
Chapter 2 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 2.1 - Prob. 1LTSCh. 2.1 - Prob. 3ATSCh. 2.2 - Prob. 2LTSCh. 2.2 - Prob. 4PTSCh. 2.2 - Prob. 6ATSCh. 2.4 - Prob. 3LTSCh. 2.4 - Prob. 9ATSCh. 2.5 - Prob. 4LTSCh. 2.5 - Prob. 11PTSCh. 2.9 - Prob. 6LTS
Ch. 2.9 - Prob. 15PTSCh. 2.9 - Prob. 16PTSCh. 2.10 - Prob. 18CCCh. 2.10 - Prob. 19CCCh. 2.10 - Prob. 20CCCh. 2.10 - Prob. 21CCCh. 2.10 - Prob. 22CCCh. 2.10 - Prob. 23CCCh. 2.10 - Prob. 24CCCh. 2.10 - Prob. 25CCCh. 2 - Prob. 34PPCh. 2 - Prob. 35PPCh. 2 - Prob. 36PPCh. 2 - Prob. 37PPCh. 2 - Prob. 38PPCh. 2 - Prob. 40PPCh. 2 - Prob. 42PPCh. 2 - Prob. 43PPCh. 2 - Prob. 44PPCh. 2 - Prob. 45PPCh. 2 - Prob. 46PPCh. 2 - Prob. 47PPCh. 2 - Prob. 48PPCh. 2 - Prob. 49PPCh. 2 - Prob. 50PPCh. 2 - Prob. 67ASP
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- an organic compound containing an aromatic six-membered ring (benzene) and a carboxylic acid functional group has a molecular formula of C6H5CO2H. Draw the corresponding skeletal structurearrow_forwardFollowing the rule that each atom of carbon, oxygen, and nitrogen reacts to achieve a complete outer shell of eight valence electrons, add unshared pairs of electrons as necessary to complete the valence shell of each atom in these ions. Then assign formal charges as appropriate.arrow_forwardConvert each of the following molecular models into a skeletal structure, and give the formula of each. Only the connections between atoms are shown; multiple bonds are not indicated (gray = C, red = O, blue = N, ivory = H).arrow_forward
- NH2(-) a) How many lone pairs (non-bounding electron pairs) does the compound possess on All atoms? (central atom(s) and outer atoms? b) For this compound, Identify the following -number of electron groups (electron domains) number of atoms bounded to the central atom number of non-bounding electron pairs (lone pairs) attached to the central atom General formula c) What is the Electron group Geometry also called "overall shape" and Hybrid Orbital designation for the central atm? d)What is the shape the atoms make (excluding the lone pairs)? This is also called the 'molecular shape"arrow_forwardDetermine the number of lone pairs on the nitrogen atom in the following structures.arrow_forwardWhat orbital do the lone-pair electrons occupy in each of the following compounds?arrow_forward
- Describe the geometry shape around a carbon atom which has 4 single bonds to its neighboring atoms. What is the approximate angle between any two of these bond directions?arrow_forwardThe molecular formula of the following compound is C H Harrow_forwardConvert each of the following molecular models into a skeletal structure, and give the formula of each. Only the connections between atoms are shown; multiple bonds are not indicated (gray=C, red =O, blue =N, ivory = H)arrow_forward
- How many electron pairs are shared when a triple bond exists between two carbon atoms? What must he the geometric arrangement around the carbon atoms in a triple bond? Draw the Lewis structure of a simple molecule that contains a triple bond.arrow_forwardWhat is the molecular formula for the following bond-line structures? H,arrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name dimethyl ether iodomethane acetic acid compound formula or Lewis structure H T H-C-Ö-C-H I H HILIA CH₂I | H H :O: | || H-C-C-O-H Between molecules of the compound? O yes O no O yes O no hydrogen-bonding force O yes O no Between molecules of the compound and molecules of water? O yes Ono O yes O no O yes O no X Sarrow_forward
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