Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 22, Problem 75GQ
Give a systematic name or the formula for the following:
(a) (NH4)2[CuCl4]
(b) tetraaquadichlorochromium(III) chloride
(c) aquabis(ethylenediamine) thiocyanatocobalt(III) nitrate
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Chapter 22 Solutions
Chemistry & Chemical Reactivity
Ch. 22.4 - (a) What is the formula of a complex ion composed...Ch. 22.4 - (a) Determine the metals oxidation number and...Ch. 22.4 - Name the following coordination compounds. (a)...Ch. 22.5 - What types of isomers are possible for the...Ch. 22.6 - Prob. 22.5CYUCh. 22.7 - Prob. 22.6CYUCh. 22.7 - Prob. 1.1ACPCh. 22.7 - Copper has a face-centered cubic unit cell. If...Ch. 22.7 - Prob. 1.3ACPCh. 22.7 - If a patient is given 10.0 mg of cisplatin, what...
Ch. 22.7 - Prob. 2.2ACPCh. 22.7 - How are the d electrons of Pt distributed in a...Ch. 22.7 - What are the electron configurations for Nd and...Ch. 22.7 - Prob. 3.2ACPCh. 22.7 - Prob. 3.3ACPCh. 22.7 - Prob. 3.4ACPCh. 22 - Identify, based on the position in the periodic...Ch. 22 - Prob. 2PSCh. 22 - Prob. 3PSCh. 22 - Prob. 4PSCh. 22 - Prob. 5PSCh. 22 - Iron is the most abundant transition element in...Ch. 22 - Prob. 7PSCh. 22 - Prob. 8PSCh. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - The lanthanide contraction is given as an...Ch. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Prob. 17PSCh. 22 - Prob. 18PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33PSCh. 22 - Prob. 34PSCh. 22 - Prob. 35PSCh. 22 - Prob. 36PSCh. 22 - Prob. 37PSCh. 22 - Prob. 38PSCh. 22 - Prob. 39PSCh. 22 - Prob. 40PSCh. 22 - Prob. 41PSCh. 22 - Prob. 42PSCh. 22 - Prob. 43PSCh. 22 - Prob. 44PSCh. 22 - Prob. 45PSCh. 22 - Prob. 46PSCh. 22 - Prob. 47PSCh. 22 - Prob. 48PSCh. 22 - Prob. 49PSCh. 22 - Prob. 50PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 52PSCh. 22 - Prob. 53GQCh. 22 - Prob. 54GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 56GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 58GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 61GQCh. 22 - Prob. 62GQCh. 22 - Prob. 63GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 65GQCh. 22 - Prob. 66GQCh. 22 - Prob. 67GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 69GQCh. 22 - Prob. 70GQCh. 22 - Prob. 71GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 77GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 79GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 84GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 89SCQCh. 22 - Prob. 90SCQ
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- Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardPredict the number of unpaired electrons.(a) K3[CrI6](b) [Cu(en)2(H2O)2]Cl2(c) Na3[Co(NO2)6]arrow_forward
- What is the oxidation state of Iron (Fe) in K3[Fe(C2O4)3.3H2O?arrow_forwardGive the systematic name for each of the following chemical compounds:(a) [Ni(OH2)4(OH)2](b) [HgClI](c) K4[Os(CN)6](d) [FeBrCl(en)2]Clarrow_forward(i) What type of isomerism is shown by the complex [Cr(H2O)6]Cl3?(ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P.(iii) Write the hybridization and shape of [CoF6]3-.(Atomic number of Co = 27)arrow_forward
- What type of isomerism is shown by the complex [Cr(H20)6]Cl3? (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P. (iii) Write the hybridization and shape of [CoF6]3-. (Atomic number of Co = 27)arrow_forwardDraw the geometrical isomers of complex [Pt(NH3)2Cl2]. (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 < P. (ii) Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].arrow_forwardDraw orbital-energy splitting diagrams and use the spectro-chemical series to show the orbital occupancy for each of the fol-lowing (assuming that H₂O is a weak-field ligand):(a) [Fe(C₂O₄)₃]³⁻(C₂O₄²⁻creates a weaker field than H₂O does.)(b) [Co(CN)₆]⁴⁻(c) [MnCl₆]⁴⁻arrow_forward
- The complexes [V(H2O)6]3+ and [VF6]3- are both known.(a) Draw the d-orbital energy-level diagram for V(III) octahedralcomplexes. (b) What gives rise to the colors of thesecomplexes? (c) Which of the two complexes would youexpect to absorb light of higher energy?arrow_forwardDraw orbital-energy splitting diagrams and use the spectro-chemical series to show the orbital occupancy for each of the fol-lowing (assuming that H₂O is a weak-field ligand):(a) [Cr(CN)₆]³⁻(b) [Rh(CO)₆]³⁺(c) [Co(OH)₆]⁴⁻arrow_forwardWhich of these compounds is expected to be colorless? (A) K4[Fe(CN)6] (B) K4[Co(CN)6] (C) K2[Ni(CN)4] (D) K2[Zn(CN)4]arrow_forward
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