Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 21.SE, Problem 76AP
Interpretation Introduction
Interpretation:
To draw the structure of the
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
20:32
hydroxide
2. Using curved arrows, show the deprotonation mechanism of phenol with
(OH). Also, provide the structure of the product of this deprotonation.
Start answering this question by drawing the structure of phenol. Then
hydroxide ion. Find your most reactive electrons and draw the curved arrow that
shows where they would go to deprotonate phenol. Then "make a bond break a
bond"
write they
question
3. Provide valid resonance structures for the product of
the previous
arrow(s)
charge moving onto the ortho- and para positions. Use curved
to show how the charge resonates to the next structure in your scheme.
all the proper notations for depicting resonance.
that show the
in the structures
Be sure to use
Send a chat
C
15. In organic synthesis, sodium methoxide (NaOCH3) is useful as a strong base and as a
nucleophile. Sodium methoxide can easily be prepared by reacting which one of the
following with methanol? (Hint: This reaction is seen in the pyrimethamine synthesis.)
A) sodium chloride
B) sodium sulfate
C) sodium hydroxide
D) sodium metal
E) sodium nitrite
16. The reaction of ferrocene with acetic anhydride to form acetylferrocene and
diacetylferrocene is an example of which type of reaction?
A) a Grignard reaction
B) a Wittig reaction
C) a Friedel-Crafts reaction
D) a Diels-Alder reaction
E) a reductive amination reaction
21. Give 2 different one-step methods to convert propanoic acid to methyl propanoate.
Chapter 21 Solutions
Organic Chemistry
Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3PCh. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6PCh. 21.3 - Prob. 7PCh. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P
Ch. 21.4 - Prob. 11PCh. 21.4 - Prob. 12PCh. 21.4 - Prob. 13PCh. 21.5 - Prob. 14PCh. 21.5 - What product would you expect from reaction of one...Ch. 21.6 - Prob. 16PCh. 21.6 - Prob. 17PCh. 21.6 - Show the products you would obtain by reduction of...Ch. 21.6 - What ester and what Grignard reagent might you...Ch. 21.7 - Prob. 20PCh. 21.7 - How would you use the reaction of an amide with...Ch. 21.8 - Write the mechanism of the reaction shown in...Ch. 21.9 - Prob. 23PCh. 21.9 - Prob. 24PCh. 21.10 - Prob. 25PCh. 21.10 - Prob. 26PCh. 21.SE - Name the following compounds:Ch. 21.SE - Prob. 28VCCh. 21.SE - Prob. 29VCCh. 21.SE - Prob. 30VCCh. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the complete...Ch. 21.SE - Prob. 35MPCh. 21.SE - When 4-dimethylaminopyridine (DMAP) is added in...Ch. 21.SE - Prob. 37MPCh. 21.SE - Prob. 38MPCh. 21.SE - Prob. 39MPCh. 21.SE - The hydrolysis of a biological thioester to the...Ch. 21.SE - Prob. 41MPCh. 21.SE - Prob. 42MPCh. 21.SE - Prob. 43MPCh. 21.SE - In the iodoform reaction, a triiodomethyl ketone...Ch. 21.SE - Give IUPAC names for the following compounds:Ch. 21.SE - Prob. 46APCh. 21.SE - Draw and name compounds that meet the following...Ch. 21.SE - Predict the product, if any, of reaction between...Ch. 21.SE - Prob. 49APCh. 21.SE - Prob. 50APCh. 21.SE - What product would you expect to obtain from...Ch. 21.SE - Prob. 52APCh. 21.SE - Prob. 53APCh. 21.SE - The following reactivity order has been found for...Ch. 21.SE - Prob. 55APCh. 21.SE - Outline methods for the preparation of...Ch. 21.SE - Prob. 57APCh. 21.SE - When ethyl benzoate is heated in methanol...Ch. 21.SE - tert-Butoxycarbonyl azide, a reagent used in...Ch. 21.SE - Prob. 60APCh. 21.SE - Prob. 61APCh. 21.SE - What is the structure of the polymer produced by...Ch. 21.SE - Polyimides with the structure shown are used as...Ch. 21.SE - Prob. 64APCh. 21.SE - Propose a structure for a compound, C4H7ClO2, that...Ch. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Prob. 67APCh. 21.SE - When a carboxylic acid is dissolved in...Ch. 21.SE - Prob. 69APCh. 21.SE - Prob. 70APCh. 21.SE - Prob. 71APCh. 21.SE - Phenyl 4-aminosalicylate is a drug used in the...Ch. 21.SE - N,N-Diethyl-m-toluamide (DEET) is the active...Ch. 21.SE - Tranexamic acid, a drug useful against blood...Ch. 21.SE - One frequently used method for preparing methyl...Ch. 21.SE - Prob. 76APCh. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Propose structures for compounds with the...Ch. 21.SE - Propose a structure for the compound with the...Ch. 21.SE - Draw the structure of the compound that produced...Ch. 21.SE - Prob. 81APCh. 21.SE - Epoxy adhesives are prepared in two steps. SN2...
Knowledge Booster
Similar questions
- After treating the activated carbon with sulfuric acid or any acid, I found out that it is needed to wash it with deionized water or distilled water, why is that so? Please explain in detail.arrow_forward20. Some alcohols undergo rearrangement or other unwanted side reactions when they dehydrate in acid. Alcohols may be dehydrated under mildly basic conditions using phosphorus oxychloride (POCI3) in pyridine. The alcohol reacts with phosphorus oxychloride much like it reacts with tosyl chloride, displacing a chloride ion from phosphorus to give an alkyl dichlorophosphate ester. The dichlorophosphate group is an outstanding leaving group. Pyridine reacts as a base with the dichlorophosphate ester to give an E2 elimination. Propose a reasonable mechanism for the dehydration of 2- methylcyclohexanol by POCl 3 in pyridine.arrow_forwardWill an amide be the final product obtained from the reaction of an acyl chloride with pyridine in an aqueous solution? Explain your answer.arrow_forward
- 3. When aspirin is made from acetic acid, the by product is H₂O; when acetic anhydride is used, the by-product is acetic acid. When acetyl chloride is used (see above), the by product is HCl. Which route should you use if you were working for Leica, a company that mass produces aspirin on a daily basis? Why?arrow_forwardWill an amide be the final product obtained from the reaction of an acyl chloride with pyridine in an aqueous solution?arrow_forwardWhat product would you expect to obtain from the reaction of benzene compound with chloroethane and aluminum chloride, AICI3.arrow_forward
- what is the best way to come up with how to synthesize carboxylic acid , oct-4-yne to butanoic acid, or trans cyclodecene to decanedoic acid . I keep getting confused on how to go from the reactants to product, even with the amines. i can't figure out what to use to get to the product. Please explain Grignard rx as well.arrow_forward1. What is the reaction Benzoic acid+ NaOH+H20+HCL yield? Please write in chemical structure ! 2. What is the reaction p-nitroaniline + H2O+ HCL+ NaOH yield?arrow_forwardwhy can polymer catalysts Amberlyst 15 be used instead of concentrated phosphoric acid in the dehydration of alcohols Why would this approach be considered “greener”?arrow_forward
- 1. What type of reaction explains the solubility of phenol in Sodium Hydroxide? Explain the organic product formed 2. How do the reactions of phenol samples with FeCl3 compare? Which structural component of the phenols account for the observation? 3. What compound is the precipitate formed in the Bromine water test? 4. Write the reaction formed in the formation of phenolphthalein. Identify the functional group in phenolphthalein , which is responsible for the indicator property. 5. What is the significance of Millon's test?arrow_forwardWhat is the major product when vanillin reacts with acetic anhydride in the presence of sulfuric acid? Could you please give me the reaction with the Lewis structures.arrow_forwardWrite the equation for the following reactions. Name and write the structure of the major product formed in the given reaction. a. isopentylbromide + NH3(aq) b. N,N-dimethylaniline + acetic acid c. ethyl-n-butylamine + benzyl chloride d. ethylpropylamine + benzoyl chloride e. isopentylamine + acetoyl chloridearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning