(a)
Interpretation:
The mechanism for the hydrolysis of the given compound under basic conditions is to be drawn, the product that contains
Concept introduction:
Hydrolysis of esters occurs under acidic and basic conditions. Carboxylate ion and alcohol are obtained by the hydrolysis of ester under basic condition whereas;
(b)
Interpretation:
The mechanism for the hydrolysis of the given compound under acidic conditions is to be drawn, the product that contains
Concept introduction:
Hydrolysis of esters occurs under acidic and basic condition. Carboxylate ion and alcohol are obtained by the hydrolysis of ester under basic condition whereas; carboxylic acid and alcohol are obtained from the hydrolysis of ester under acidic condition.
(c)
Interpretation:
An experimental proof for the position of
Concept introduction:
The replacement of atom with its isotope in a chemical compound is termed as isotope labelling. The physical and chemical properties of compound change on attachment of isotope to it.
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Organic Chemistry (9th Edition)
- Complete the mechanism for the reaction of butanone with NaBH, followed by the addition of aqueous acid. 1. NABH4 final product 2. H3O* Step 2: Draw the charged organic intermediate product. Include nonbonding electrons and Step 1: draw curved arrows. Select Draw Rings More Erase charges. Omit the counterion. HB Na o C Select Draw Rings More Erase C H В :0 : H. H, O* H - B Na + ↑arrow_forwardhelp me pleasearrow_forward10. Explain the reaction shown below. Include the following pieces in your explanation. Identify the electrophile and the nucleophile. Draw a curved arrow mechanism for this reaction. (Assume an acidic work-up). Explain the electron flow. Indicate any regiochemical or stereochemical preferences. one b. c. d. LIAIH4 OH onearrow_forward
- [References) Draw the structure of the product obtained when this amine is treated with excess iodomethane and then heated with Ag,0 (Hoffman elimination). ball & stickv + labels • Consider E/Z stereochemistry of alkenes. • Draw only the elimination product, do not the leaving group. • In cases where there is more than one answer, just draw one.arrow_forwardAcyl transfer (nucleophilic substitution at carbonyl) reactions proceed in two stages via a "tetrahedral intermediate." Draw the tetrahedral intermediate as it is first formed in the following reaction. H3C. ... NH2 HCI/H₂O reflux • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. • Do not include counter-ions, e.g., Na+, I, in your answer. • In cases where there is more than one answer, just draw one. + 4 n [ ?arrow_forwardDraw structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol or enone below. • You do not have to consider stereochemistry. • Draw the enolate ion in its carbanion form. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple reactants using the + sign from the drop-down menu. ChemDoodle Submit Answer Retry Entire Group 7 more group attampts remalningarrow_forward
- 4. Explain the reaction shown below. Include the following pieces in your explanation. a. Identify the electrophile and the nucleophile. b. Draw a curved arrow mechanism for this reaction. (Assume an acidic work-up). Explain the electron flow. C. d. Indicate any regiochemical or stereochemical preferences. H₂C OCH₂ H+ HO,... CH₂OHarrow_forwardCurved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. H. BH₂ BH₂ THF . Draw Major Borane Intermediate H2O2, NaOH Draw Major Productarrow_forward3. Answer the following questions based on the reaction scheme below. a. Use wedged and dashed lines to draw the (2S,4R)-2-iodo-4-methoxypentane configuration of 2-iodo-4-methoxypentane in labeled box. b. Draw the product(s) of the nucleophilic addition reaction shown. Make sure to use wedged and dashed lines to clearly show the resulting stereochemistry at each chiral center. Label each chiral center as R or S. If there is more than one possible product, draw one in each box - if not, leave one box blank. c. Write the correct chemical name of each product(s) in the labeled boxes. 2-iodo-4- methoxypentane + NaOCH 3 K[C6H1310] Product Name: Product Name: d. Are all the product(s) chiral? If your answer is 'yes' write 'yes' in the box below. If your answer is 'no', provide an explanation in 3 sentences or less in the box below.arrow_forward
- For each reaction, decide whether the reaction is a redox reaction, acid-base reaction, electrophile- nucleophile, or something else. One can begin to identify the type of reaction by looking to see if oxidation numbers of atoms that take part in the reaction change during the reaction. You will need to draw out the structures. a. If the reaction is considered an acid- base reaction, draw out the full mechanism for the reaction. Be sure to indicate which compound is the acid, base, and conjugate acid and base (where possible). b. If the reaction is considered a redox reaction, be sure to indicate which species are oxidized and which are reduced. c. For every reaction you will need to justify your identification of the type of reaction.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the product of this elementary step in an SN1 mechanism. + Include all lone pairs and charges as appropriate. Ignore stereochemistry. Ignore byproducts. Nal <arrow_forwarde. f. Draw in any lone pairs of electrons that are directly involved in the reaction. or distributed d. Draw the elimination product that would form upon reaction of (4S)-1-bromo-4- methylhexane with KOC(CH3)3 in HOC(CH3)3 solvent. (Include Would this reaction be E1 or E2? de stereochemistry) may not be sha Draw a detailed step-wise mechanism for this elimination reaction. Be sure to include all steps, formal charges, and show the movement of electrons with curved arrows. Draw in any lone pairs of electrons that are directly involved in the reaction. msider the following reactions Indicate which mechanism(s) would be occurring (S1 S2 F1arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning