Concept explainers
(a)
Interpretation:
The product with detailed mechanism for the reaction between
Concept introduction:
An acid chloride can be converted to corresponding
Answer to Problem 20.45P
The product with detailed mechanism for the reaction between
Explanation of Solution
The equation for the reaction of
The product with detailed mechanism for the given reaction is drawn based on the reactivity of
(b)
Interpretation:
The product with detailed mechanism for the reaction between
Concept introduction:
An acid chloride can be converted to an
Answer to Problem 20.45P
The product with detailed mechanism for the reaction between
Explanation of Solution
The equation for the reaction of
The product with detailed mechanism for the given reaction is drawn based on the reactivity of
(c)
Interpretation:
The product with detailed mechanism for the reaction between
Concept introduction:
An acid chloride can be converted to a primary alcohol by reacting with
Answer to Problem 20.45P
The product with detailed mechanism for the reaction between
Explanation of Solution
The equation for the reaction of
The product with detailed mechanism for the given reaction is drawn based on the reactivity of
(d)
Interpretation:
The product with detailed mechanism for the reaction between
Concept introduction:
An acid chloride can be converted to a tertiary alcohol by reacting it with
Answer to Problem 20.45P
The product with detailed mechanism for the reaction between
Explanation of Solution
The equation for the reaction of
The product with detailed mechanism for the given reaction is drawn based on the reactivity of
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Chapter 20 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
- Draw the structure of the hydroxyaldehyde product from the self-aldol reaction of each of the following aldehydes: (a) propanal; (b) phenylethanal; (c) 3-phenylpropanal; (d) benzaldehyde.arrow_forward22. Provide the following: 1) the major organic product of each reaction shown, and ii) the specific name of the reaction in the first step. aniline AICI (if o,p-substituted products are possible, only provide the major para-substituted product, otherwise, only provide the meta-substituted product) 12, HNO (if o,p-substituted products are possible, only provide the major para-substituted product, otherwise, only provide the meta-substituted product) end a chatarrow_forward1// In a set of the given reactions, acetic acid yielded a product C C6 H6 C HM9B CH;COOH + PCl, → A anh. AlCl ether What would be product C? 2// When propionic acid is treated with aqueous sodium bicarbonate formed? 3// When CH3COOH reacts with CH3-Mg-X formed? 4// What is the product in the given reaction when benzyl chloride reacts with benzen?arrow_forward
- Determine whether each of the following syntheses requires a reaction that alters the carbon skeleton. (a) (b) OH (c) (d) OCH,CH3 CH3 (e) OH (f) H,CO он H;CO. (g) H3CO, (h) H3CO. NO2 NO2arrow_forwardDraw the product formed when CH3CH2C=CH is treated with each of the following sets of reagents: (a) H2O, H2SO4, HgSO4; and (b) R2BH, followed by H2O2, HO−.arrow_forwardName the structure. Heating compound A in the presence of H2SO4 results in which product?arrow_forward
- 10. Compound X (C4H9Br) reacts by heating with NaOH in H2O to form Y. The compound Y then undergoes acid catalysed hydration by H2SO, in 180°C to form 2-methyl prop-1-ene. (e) Determine the structure of X and Y. (f) Predict a MAJOR product when compound Y reacts with H2SO4 in 140 C. (g) Draw a structural isomer of X. Name the isomer using IUPAC nomenclature. (h) Describe a chemical test to distinguish between compound Y and 1-butanol.arrow_forward4. identify the structure of A and B in the following synthetic scheme: Write out complete reactions for each step, showing the structure of all reactants and products. (a) cyclohexanol +Na2Cr2O7/H2SO4, H2O -------> A (b) A + Et2NH/H2SO4 ----->Barrow_forwardDevise at least three different methods to prepare N-methylbenzylamine (PhCH2NHCH3) from benzene, any one-carbon organic compounds, and any required reagents.arrow_forward
- (a) Draw two different enol tautomers of 2-methylcyclohexanone. (b) Draw two constitutional isomers that are not tautomers, but contain a C=C and an OH group. 2-methylcyclohexanonearrow_forwardGive the major product of the following reaction. CH;CH,OH CIarrow_forwardAlkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two O Hint in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. The first step of the reaction, hydroboration, involves addition of BH, to the double bond, with -BH, attached to one carbon and hydrogen Be sure to draw hydrogens on oxygen, where applicable. attached to the other. Consider both Rings the regioselectivity and the Select Draw More Erase stereochemistry of this addition. H Diborane, B,H,, is a source of borane, BH,, and can be used 1. B2H6, interchangeably. Diglyme is a solvent. diglyme 2. H2О2, НО", The product or products of the reaction are characterized as being O S. O racemic. O achiral. O R,S (and/or S,R). O R. O S,S. O R.R. O diastereomers.arrow_forward
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