Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 20, Problem 20.34E
When ionic compounds crystallize from a supersaturated solution, the crystallization front (that is, the barrier between the crystalline solid and the supersaturated solution) typically travels at a constant speed through the solution until it reaches the boundaries of the system, then stops. What order of rate law is described by this behavior?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Granulated sugar is added to a saturated sugar solution. Give the number of components and phases of the system and identify them! What is the thermodynamic (Gibbs’) degree of freedom of the equilibrium state? Provide full explanation!
What is the rate law in respect to the solution and what is the k for the reaction?
This is a question for the Reaction of sodium metals with alcohols.
In the experiment there are three alcohol samples namely Ethyl alcohol, isopropyl alcohol, and Tert-Butyl alcohol. It was then observed that
Ethyl alcohol > isopropyl alcohol> tertiary butyl alcohol
Where ethyl alcohol has the most bubbles formed while the number of bubbles decreases on isopropy and tert butyl. What does the bubble reaction simply implies on each alcohol sample. Explain your answer
Chapter 20 Solutions
Physical Chemistry
Ch. 20 - Prob. 20.1ECh. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The rate of the reaction...Ch. 20 - For a certain reaction between NO and O2, the rate...Ch. 20 - For a reaction between SO2 and Cl2, the rate law...Ch. 20 - Consider the chemical reaction A+B+Cproducts...Ch. 20 - For the chemical reaction...Ch. 20 - Explain how a species might be part of a rate law...Ch. 20 - Refer to Example 20.2 and explain whether any...
Ch. 20 - Rate law experiments dont always give data in the...Ch. 20 - Prob. 20.12ECh. 20 - What must the units on k be for the following rate...Ch. 20 - What must the units on k be for the following rate...Ch. 20 - The reaction 2O33O2 has first-order kinetics and a...Ch. 20 - Digestive processes are first-order processes. The...Ch. 20 - Prob. 20.18ECh. 20 - Derive equation 20.15.Ch. 20 - Prob. 20.20ECh. 20 - To a very good approximation, the cooling of a hot...Ch. 20 - Assume that thermal decomposition of mercuric...Ch. 20 - Prob. 20.23ECh. 20 - Prob. 20.24ECh. 20 - Derive equation 20.22.Ch. 20 - a Write a rate law and an integrated rate law for...Ch. 20 - Derive an expression for the half-life of a a...Ch. 20 - Prob. 20.28ECh. 20 - Rewrite equation 20.27 so that it has the form of...Ch. 20 - One can also define a third-life, t1/3, which is...Ch. 20 - The decomposition of NH3: 2NH3N2+3H2 is a...Ch. 20 - Prob. 20.32ECh. 20 - Prob. 20.33ECh. 20 - When ionic compounds crystallize from a...Ch. 20 - An aqueous reaction that uses the solvent H2O as a...Ch. 20 - The rate law for the reaction...Ch. 20 - If a reaction has the same rate constant, what...Ch. 20 - List at least four experimentally determined...Ch. 20 - Prob. 20.39ECh. 20 - Prob. 20.40ECh. 20 - Prob. 20.41ECh. 20 - Prob. 20.42ECh. 20 - What is the value of the equilibrium constant of a...Ch. 20 - Prob. 20.44ECh. 20 - Prob. 20.45ECh. 20 - Show how equation 20.33 reduces to a simpler form...Ch. 20 - Write expressions like equation 20.37 for a set of...Ch. 20 - Prob. 20.48ECh. 20 - Prob. 20.49ECh. 20 - Prob. 20.50ECh. 20 - Prob. 20.51ECh. 20 - Prob. 20.52ECh. 20 - Prob. 20.53ECh. 20 - Prob. 20.54ECh. 20 - For what values of time, t, will 210Bi and 206Pb...Ch. 20 - Prob. 20.56ECh. 20 - An interesting pair of consecutive reactions...Ch. 20 - Find limiting forms of equation 20.47 for a k1>>k2...Ch. 20 - Prob. 20.59ECh. 20 - Prob. 20.60ECh. 20 - Prob. 20.61ECh. 20 - Prob. 20.62ECh. 20 - At room temperature (22C), the rate constant for...Ch. 20 - Recently, researchers studying the kinetics of...Ch. 20 - A reaction has k=1.771061/(Ms) at 25.0C and an...Ch. 20 - Prob. 20.66ECh. 20 - Prob. 20.67ECh. 20 - Prob. 20.68ECh. 20 - Nitric oxide, NO, is known to break down ozone,...Ch. 20 - a Suggest a mechanism for the bromination of...Ch. 20 - Prob. 20.71ECh. 20 - Prob. 20.72ECh. 20 - Determine a rate law for the chlorination of...Ch. 20 - Determine a rate law for the chlorination of...Ch. 20 - A proposed mechanism for the gas-phase...Ch. 20 - Prob. 20.76ECh. 20 - The nitration of methanol, CH3OH, by nitrous acid...Ch. 20 - Prob. 20.78ECh. 20 - Many gas-phase reactions require some inert body,...Ch. 20 - Prob. 20.80ECh. 20 - Carbonic anhydrase, an enzyme whose substrate is...Ch. 20 - Show that another form of the Michaelis-Menten...Ch. 20 - Prob. 20.83ECh. 20 - Prob. 20.84ECh. 20 - Prob. 20.85ECh. 20 - Prob. 20.86ECh. 20 - Pyrolysis involves heating compounds to break them...Ch. 20 - Prob. 20.88ECh. 20 - Label the elementary processes for the reaction...Ch. 20 - Prob. 20.90ECh. 20 - What are the rate laws of mechanisms 1 and 2 for...Ch. 20 - Estimate G for an elementary process whose rate...Ch. 20 - Prob. 20.93ECh. 20 - Prob. 20.94ECh. 20 - Prob. 20.95ECh. 20 - For the following two reactions H+Cl2HCl+Cl...Ch. 20 - Prob. 20.97ECh. 20 - Prob. 20.98ECh. 20 - Prob. 20.99ECh. 20 - Consider a reaction that has two parallel pathways...Ch. 20 - Consider a set of first-order consecutive...Ch. 20 - Prob. 20.102E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider the following solutions: Sodium chloride s in water Sucrose s in water C20H42(s) in cyclohexane Water in carbon tetrachloride For which solutions do you think that a calculated solubility will be close to the experimental solubility? Explain your reasoning.arrow_forwardShow that another form of the Michaelis-Menten equation is rate=V[S]K+[S]arrow_forwardThe third part of equation 4.9 mentions a condition called equilibrium, in which there is no net change in the state of a system. What are the equilibrium conditions for dU, dH, and dA?arrow_forward
- The solubility of cerium sulphate solution decreases with increase in temperature. This because entropy increases with temperature O the net enthalpy change is positive O dissolution of cerium sulphate is an exothermic process dissolution of cerium sulphate is an endothermic processarrow_forwardBromine monochloride is synthesized using the reaction Br, (g) + Cl, (g) = 2 BrCl(g) K, = 1.1 x 104 at 150 K A 193.0 L flask initially contains 0.956 kg of Br, and 1.014 kg of Cl,. Calculate the mass of BrCI, in grams, that is present i the reaction mixture at equilibrium. Assume ideal gas behavior. 11.45 mass of BrCl: Incorrect What is the percent yield of BrCI? percent yield: 81arrow_forwardProvide the possible candidate ion/s for the primary adsorbed layer of a colloid formed when small amounts of silver nitrate is added to a solution of potassium chromate by accounting the following five factors: solubility, concentration, common ion, ion charge and ion size. Write the colloid formula.arrow_forward
- pressure plays an vital role in the solubility of gas in liquid. Solubility is the amount of solute dissolved in solvent. With increasing in the pressure on the liquid system, solubility of gas in liquid increases. As per Henry’s Law, at constant temperature, the mass of a gas dissolved per unit volume of solvent is directly proportional to the pressure of gas in equilibrium. Solute - Solid substanceSolvent - Liquid substance. Solute is mixed into solvent to form solution and solubility is the amount of a substance (solute) mixed in a particular solvent to form solution.When temperature increases -the average kinetic energy of the liquid molecules increases. This increased kinetic energy makes the liquid molecules creating more space between them.With increase in temperature, the intermolecular forces holding the solid particles also decrease. This leads to break them into smaller pieces and makes them readily take space vacant between the liquid particles. This way more solute is…arrow_forwardConsider a crystallization of sulfanilamide in which 10 mL of hot 95% ethyl alcohol is added to 0.10 g of impure sulfanilamide. After the solid has dissolved, the solution is cooled to room temperature and then placed in an ice-water bath. No crystals form, even after scratching with a glass rod. Explain why this crystallization failed. What would you have to do at this point to make the crystallization work? Assume that starting over again with a new sample is not an option.arrow_forwardThe student collects the H2(g) produced by the reaction and measures its volume over water at 298 K after carefully equalizing the water levels inside and outside the gas-collection tube, as shown in the diagram below. The volume is measured to be 45.6mL . The atmospheric pressure in the lab is measured as 765 torr , and the equilibrium vapor pressure of water at 298 K is 24 torr. 1. Find the number of moles of H2 (g) produced in the reaction.arrow_forward
- 7.50. What is the approximate molarity of a saturated solution of phenol, , for which can be dissolved in of water. The density of phenol is ; assume ideal behavior with respect to the total volume of the solution?arrow_forwardWhen 19.77g of glucose, C6H12O6(180.2g/mol), is dissolved in 225.6g of an organic solvent, the freezing point of the resulting solution is 1.06C lower than that of the pure solvent. What is the molality of the solution? What is the value of Kf for the solvent?arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Intermolecular Forces and Boiling Points; Author: Professor Dave Explains;https://www.youtube.com/watch?v=08kGgrqaZXA;License: Standard YouTube License, CC-BY