Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 2, Problem 2.93E
Find the enthalpies of the combustion reactions for methane through n-octane. Plot them versus the number of carbon atoms in the molecule, and determine an equation that gives ΔH for the combustion of a given hydrocarbon. Then use the equation to predict the enthalpy of combustion for n-C12H26 and compare it to experimental values.
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Physical Chemistry
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- A compound is 82.7% carbon and 17.3% hydrogen, and has a molar mass of approximately 60 g/mol. When 1.000 g of this compound burns in excess oxygen, the enthalpy change is 49.53 kJ. (a) What is the empirical formula of this compound? (b) What is the molecular formula of this compound? (c) What is the standard enthalpy of formation of this compound? (d) Two compounds that have this molecular formula appear in Appendix G. Which one was used in this exercise?arrow_forwardCamping stoves are fueled by propane (C3H8), butane [C4H10(g), fH = 127.1 kJ/mol]. gasoline. or ethanol (C2H5OH). Calculate the enthalpy of combustion per gram of each of these fuels. [Assume that gasoline is represented by isooctane, C8H18(), with fH = 259.3 kJ/mol.) Do you notice any great differences among these fuels? How are these differences related to their composition?arrow_forwardAlthough the gas used in an oxyacetylene torch (Figure 5.7) is essentially pure acetylene, the heat produced by combustion of one mole of acetylene in such a torch is likely not equal to the enthalpy of combustion of acetylene listed in Table 5.2. Considering the conditions for which the tabulated data are reported, suggest an explanation.arrow_forward
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