(a) Interpretation: The structure for the isomeric amides having the molecular formula C 4 H 9 NO is to be drawn. Concept introduction: Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

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Answer 1

Question

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

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Students have asked these similar questions

(a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.

Draw and name compounds that meet these descriptions:(a) Three different amides with the formula C6H13NO(b) Three different esters with the formula C5H10O2

The five parts of question 16 relate to the following three molecules: N-H А в с A (a) Which of the three molecules above are structural isomers? (b) Which of the molecules contains a carbon with linear geometry? (c) Which molecule contains a tertiary amine? (d) Which molecule only contains sp³ hybridized atoms (not including hydrogen)? (e) Which molecule is chiral? Circle the stereocentre in this molecule.

Answer 2

Question

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

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Answer 3

Question

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

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Answer 4

Question

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

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Answer 5

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

Answer 6

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Answer 7

Chapter 2, Problem 2.50AP

Interpretation Introduction

(a)

Interpretation:

The structure for the isomeric amides having the molecular formula C4H9NO is to be drawn.

Concept introduction:

Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of isomeric amides which do not contain isopropyl groups is to be drawn.

Concept introduction:

Amides are the derivatives of carboxylic acids and are generally formed when carboxylic acid reacts with ammonia followed by the release of water. Constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of compound X containing both alcohol and amine functional group and having the molecular formula C4H9NO is to be stated.

Concept introduction:

Constitutional isomers have the same molecular formulabut they differ in the pattern in which atoms are connected. They contain either different functional groups or bonding patterns or both. There are different types of isomers but constitutional isomers differ only in the spatial arrangement of atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the compound having molecular formula C4H9NO can have a nitrile group or not is to be explained.

Concept introduction:

Nitrile functional group is the group having the general formula of RC≡N. The nitrile group is also known as the cyano group and both of them can be used as a prefix in IUPAC nomenclature interchangeably.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 2 - Prob. 2.1P Ch. 2 - Prob. 2.2P Ch. 2 - Prob. 2.3P Ch. 2 - Prob. 2.4P Ch. 2 - Prob. 2.5P Ch. 2 - Prob. 2.6P Ch. 2 - Prob. 2.7P Ch. 2 - Prob. 2.8P Ch. 2 - Prob. 2.9P Ch. 2 - Prob. 2.10P

Solution Summary: The author explains that constitutional isomers have the same molecular formula but they differ in the pattern in which atoms are connected.

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Chapter 2 Solutions