Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 17.16, Problem 19P
Interpretation Introduction

Interpretation:

The other mixture of alkyl halide and sulfide that yield from the same sulfonium salt that ismentioned exampleand the selection of the combination of mixture that forms faster than the other one is to be determined.

Concept Introduction:

Sulfur is stronger nucleophile than oxygen hence it reacts with alkyl halides faster than that of ethers. The reaction of alkyl halide and sulfur follows SN2 (nucleophilic substitution) reaction and results in the formation of sulfonium salt.

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When the compound below is treated with a base, kinetic product A and thermodynamic product B,can be formed depending on the base and temperature. Draw the structures for A and B and writethe mechanism for the formation of the thermodynamic product
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Which will react faster??

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Organic Chemistry - Standalone book

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