Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 1.7, Problem 18P
Interpretation Introduction

(a)

Interpretation: The geometry around all second-row atoms in CH3COCH3 is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of groups around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

Interpretation Introduction

(b)

Interpretation: The geometry around all second-row atoms in CH3OCH3 is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of group around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

Interpretation Introduction

(c)

Interpretation: The geometry around all second-row atoms in NH2 is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of group around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

Interpretation Introduction

(d)

Interpretation: The geometry around all second-row atoms in CH3CN is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of group around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

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1. Draw all resonance structures for each of the following molecules or ions. Be sure to include curved arrows that indicate which pair of electrons are shifted in going (flowing) from one resonance structure to the next. a. b. C. 0-2,000
3. Draw all possible resonance structures to show the delocalization in the following molecule. Use curved arrow(s) to show the movement of electron pairs. Determine and circle which resonance is the most stable. Show the lone pair of electrons if necessary. a. b. C. d. CH3 å (+) CH3 : NH₂
b. Write the structure showing lone pairs of electrons and draw all possible resonance structures for Use curved arrows to track the movement of electron pairs converting one resonance contributor to the other.: c. Write the structure showing lone pairs of electrons for the molecule below and draw all . Use curved arrows to track the possible resonance structures for anionic species movement of a pair of electrons.

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Organic Chemistry (6th Edition)

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