Show how the gicven product can be synthesized from the Grignard reagent. Concept introduction: Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent . The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond. Addition of a Grignard reagent to an aldehyde / ketone followed by protonation will produce an alcohol. Thus, Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively. An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Question

Show how these four products can be synthesized from the same Grignard reagent.

Answer 1

Question

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

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Show how these four products can be synthesized from the same Grignard reagent.

Synthesize the product from the given material. Give the reagents necessary and draw out any intermediate products along the way.

Identify the best reagents to complete the following reaction.

Answer 2

Question

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

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Answer 3

Question

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

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Answer 4

Question

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

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Answer 5

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 6

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 7

Chapter 16.5, Problem 16.4P

(a)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Show how the gicven product can be synthesized from the Grignard reagent.

Concept introduction:

Alkyl or aryl magnesium halides (RMgX) are known as Grignard reagent. The Grignard reaction is an organometallic chemical reaction in which the Grignard reagent act as nucleophile and attack electrophilic carbon atom that are present within polar bonds to yield a carbon-carbon bond.

Addition of a Grignard reagent to an aldehyde/ketone followed by protonation will produce an alcohol.

Thus,

Reaction of Grignard reagent with formaldehyde or oxirane yields primary alcohol. Secondary and tertiary alcohol can be prepared by the reaction of Grignard reagent with any aldehyde (except formaldehyde) and ketone respectively.

An equimolar mixture of the two enantiomers is called racemic mixture and it is optically inactive.

Answer 14

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Answer 15

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Answer 25

Ch. 16.1 - Write the IUPAC name for each compound. Specify...Ch. 16.1 - Write structural formulas for all aldehydes with...Ch. 16.1 - Write the IUPAC name for each compound.Ch. 16.5 - Prob. 16.4P Ch. 16.6 - Prob. 16.5P Ch. 16.7 - Prob. 16.6P Ch. 16.7 - Write a mechanism for the acid-catalyzed...Ch. 16.8 - Prob. 16.8P Ch. 16.8 - The given mechanism of transamination reaction is...Ch. 16.8 - The given mechanism of transamination reaction is...

Solution Summary: The author introduces Grignard reagent, which acts as nucleophile and attacks electrophilic carbon atom to yield a carbon-carbon bond.

Chapter 16 Solutions