Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Question
Chapter 16, Problem 16.87QE
(a)
Interpretation Introduction
Interpretation:
The dominant acid-base equilibrium that results when
(b)
Interpretation Introduction
Interpretation:
The dominant acid-base equilibrium that results when
(c)
Interpretation Introduction
Interpretation:
The dominant acid-base equilibrium that results when
(d)
Interpretation Introduction
Interpretation:
The dominant acid-base equilibrium that results when
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Does the pH increase or decrease, and does it do so to a largeor small extent, with each of the following additions?(a) 5 drops of 0.1 M NaOH to 100 mL of 0.5 M acetate buffer(b) 5 drops of 0.1 M HCl to 100 mL of 0.5 M acetate buffer(c) 5 drops of 0.1 MNaOH to 100 mL of 0.5 MHCl(d) 5 drops of 0.1 MNaOH to distilled water
Calculate the pH at the following points in a titration of 40.0 mL of 0.100 M barbituric acid(Ka = 9.8 × 10−5) with 0.100 M KOH.
(a) no KOH added
(b) 20.0 mL of KOH solution added
(c)39.0 mL of KOH solution added
(d) 40.0 mL of KOH solution added
(e) 41.0 mL of KOHSketch an appropriate pH titration curve indicating the buffer region, equivalence point,and excess base region. Why is the pH at the equivalence point not 7.00?
An acid–base titration is performed: 250.0 mL of an unknownconcentration of HCl (aq) is titrated to the equivalence pointwith 36.7 mL of a 0.1000 M aqueous solution of NaOH. Whichof the following statements is not true of this titration?
(a) The HCl solution is less concentrated than the NaOH solution.(b) The pH is less than 7 after adding 25 mL of NaOHsolution. (c) The pH at the equivalence point is 7.00. (d) If anadditional 1.00 mL of NaOH solution is added beyond theequivalence point, the pH of the solution is more than 7.00.(e) At the equivalence point, the OH- concentration in thesolution is 3.67 x 10-3 M.
Chapter 16 Solutions
Chemistry: Principles and Practice
Ch. 16 - Prob. 16.1QECh. 16 -
Sketch a titration curve for the titration of...Ch. 16 - Prob. 16.4QECh. 16 - Prob. 16.5QECh. 16 - Explain why the HendersonHasselbalch equation...Ch. 16 - Prob. 16.7QECh. 16 - Prob. 16.8QECh. 16 - Prob. 16.9QECh. 16 - Prob. 16.11QECh. 16 - Prob. 16.13QE
Ch. 16 - Prob. 16.14QECh. 16 - Prob. 16.15QECh. 16 - Prob. 16.16QECh. 16 - Prob. 16.17QECh. 16 - Prob. 16.18QECh. 16 - Calculate the pH during the titration of 100.0 mL...Ch. 16 - Prob. 16.20QECh. 16 - Prob. 16.21QECh. 16 - Calculate the pH during the titration of 50.00 mL...Ch. 16 - Prob. 16.23QECh. 16 - Calculate the pH during the titration of 50.00 mL...Ch. 16 - Prob. 16.25QECh. 16 - Prob. 16.26QECh. 16 - Prob. 16.27QECh. 16 - Prob. 16.28QECh. 16 -
Calculate the pH of solutions that are
0.25 M...Ch. 16 - Prob. 16.30QECh. 16 - Prob. 16.31QECh. 16 - Prob. 16.32QECh. 16 - Prob. 16.35QECh. 16 - Prob. 16.36QECh. 16 - Prob. 16.37QECh. 16 - Prob. 16.38QECh. 16 - Prob. 16.39QECh. 16 -
How many grams of sodium acetate must be added to...Ch. 16 - Prob. 16.41QECh. 16 - Prob. 16.42QECh. 16 - A buffer solution that is 0.100 M acetate ion and...Ch. 16 - Prob. 16.44QECh. 16 - Prob. 16.45QECh. 16 - Prob. 16.46QECh. 16 - Prob. 16.47QECh. 16 - Prob. 16.48QECh. 16 - Estimate the pH that results when the following...Ch. 16 - Estimate the pH that results when the following...Ch. 16 - Prob. 16.51QECh. 16 - Prob. 16.52QECh. 16 - Prob. 16.53QECh. 16 - Prob. 16.54QECh. 16 - Prob. 16.55QECh. 16 - Prob. 16.56QECh. 16 - Prob. 16.57QECh. 16 - Prob. 16.58QECh. 16 - Prob. 16.59QECh. 16 - Consider all acid-base indicators discussed in...Ch. 16 - Prob. 16.61QECh. 16 - Chloropropionic acid, ClCH2CH2COOH, is a weak...Ch. 16 - Prob. 16.63QECh. 16 - Prob. 16.64QECh. 16 - Prob. 16.65QECh. 16 - Write the chemical equilibrium and expression for...Ch. 16 - Calculate the pH of 0.010 M ascorbic acid.Ch. 16 - Prob. 16.68QECh. 16 - Prob. 16.69QECh. 16 - Prob. 16.70QECh. 16 - Prob. 16.71QECh. 16 - Prob. 16.72QECh. 16 - Prob. 16.73QECh. 16 - Prob. 16.74QECh. 16 - Prob. 16.75QECh. 16 - Which compound in each pair is more soluble in...Ch. 16 - Prob. 16.77QECh. 16 - Prob. 16.78QECh. 16 - Prob. 16.79QECh. 16 - Calculate the pH of each of the following...Ch. 16 - Write the chemical equation and the expression for...Ch. 16 - Prob. 16.82QECh. 16 - Prob. 16.83QECh. 16 - Phenolphthalein is a commonly used indicator that...Ch. 16 - Prob. 16.85QECh. 16 - Prob. 16.86QECh. 16 - Prob. 16.87QECh. 16 - Determine the dominant acid-base equilibrium that...Ch. 16 - Prob. 16.89QECh. 16 - Prob. 16.90QECh. 16 - Prob. 16.91QECh. 16 - Prob. 16.92QECh. 16 - Prob. 16.93QECh. 16 - Prob. 16.94QECh. 16 - Prob. 16.95QECh. 16 - Prob. 16.96QECh. 16 - Prob. 16.97QECh. 16 - A monoprotic organic acid that has a molar mass of...Ch. 16 - A scientist has synthesized a diprotic organic...Ch. 16 - Prob. 16.100QECh. 16 - What is a good indicator to use in the titration...Ch. 16 - Prob. 16.102QECh. 16 - A bottle of concentrated hydroiodic acid is 57% HI...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.arrow_forward8-71 Explain why you do not need to know the chemical formula of a buffer compound to use it.arrow_forwardWhat is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.arrow_forward
- Identify the buffer system(s)the conjugate acidbase pair(s)present in a solution that contains equal molar amounts of the following: a. HF, KC2H3O2, NaC2H3O2, and NaF b. HNO3, NaOH, H3PO4, and NaH2PO4arrow_forwardSketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.arrow_forwardWhich of these combinations is the best to buffer the pH at approximately 9? Explain your choice. CH3COOH/NaCH3COO HCl/NaCl NH3/NH4Clarrow_forward
- Two samples of 1.00 M HCl of equivalent volumes are prepared. One sample is titrated to the equivalence point with a 1.00 M solution of sodium hydroxide, while the other sample is titrated to the equivalence point with a 1.00 M solution of calcium hydroxide. a Compare the volumes of sodium hydroxide and calcium hydroxide required to reach the equivalence point for each titration. b Determine the pH of each solution halfway to the equivalence point. c Determine the pH of each solution at the equivalence point.arrow_forwardDetermine the dominant acid-base equilibrium that results when each of the following pairs of solutions is mixed. Indicate the equilibrium by writing 1 for a strong acid, 3 for a weak acid, 4 for an acidic buffer, 7 for a neutral solution, 10 for a basic buffer, 11 for a weak base, and 13 for a strong base. (a) 10.0 mL of 0.15 M NaOH + 15.0 mL of 0.10 M HNO3 (b) 25.0 mL of 0.10 M HCl + 10.0 mL of 0.25 M NH3 (c) 50.0 mL of 0.050 M NaOH + 50.0 mL of 0.10 M NH3 (d) 50.0 mL of 0.10 M NH3 + 50.0 mL of 0.05 M HClarrow_forwardA solution of weak base is titrated to the equivalence point with a strong acid. Which one of the following statements is most likely to be correct? a The pH of the solution at the equivalence point is 7.0. b The pH of the solution is greater than 13.0. c The pH of the solution is less than 2.0. d The pH of the solution is between 2.0 and 7.0. e The pH of the solution is between 7.0 and 13.0. The reason that best supports my choosing the answer above is a Whenever a solution is titrated with a strong acid, the solution will be very acidic. b Because the solution contains a weak base and the acid (titrant) is used up at the equivalence point, the solution will be basic. c Because the solution contains the conjugate acid of the weak base at the equivalence point, the solution will be acidic.arrow_forward
- Each symbol in the box below represents a mole of a component in one liter of a buffer solution; represents the anion (X-), = the weak acid (HX), = H+, and =OH. Water molecules and the few H+ and OH- ions from the dissociation of HX and X- are not shown. The box contains 10 mol of a weak acid, , in a liter of solution. Show what happens upon (a) the addition of 2 mol of OH- (2 ). (b) the addition of 5 mol of OH- (5 ). (c) the addition of 10 mol of OH- (10 ). (d) the addition of 12 mol of OH- (12 ). Which addition (a)-(d) represents neutralization halfway to the equivalence point?arrow_forwardWhat is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a titration. Why should you choose an indicator so that the two points coincide? Do the pH values of the two points have to be within 0.01 pH unit of each other? Explain.arrow_forwardChoose a weak-acid/weak-base conjugate pair from which you could prepare a buffer solution with pH = 7.5. Explain how you chose the conjugate pair. Calculate the ratio [weak base]/[weak acid) required to give pH = 7.5.arrow_forward
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