General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Question
Chapter 15, Problem 15.111QP
Interpretation Introduction
Interpretation:
The order of weakest to strongest acid for the given list has to be explained.
Concept introduction:
Strong acid:
According to Arrhenius theory, a compound or a substance which completely ionized in a aqueous solution to give a hydronium ion and anion is said to be strong acid.
Strong base:
According to Arrhenius theory, a compound or a substance which completely ionized in a aqueous solution to give a hydroxide ion and cation is said to be strong base.
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Identifying the major species in weak acid or weak base...
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
1 mol of NaOH is added to
1.0 L of a 0.7M HCN
bases: O
solution.
other: O
0.3 mol of NaOH is added to
acids:
1.0 L of a solution that is
bases: O
0.8M in both HCN and
NaCN.
O other:
Identifying the major species in weak acid or weak base...
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
1.9 mol of KOH is added to
1.0 L of a 1.0M HCN
bases:
solution.
O other:
0.095 mol of HNO, is added
O acids:
to 1.0 L of a solution that is
bases:
1.4M in both HCN and
KCN.
O other: O
O D O
O D
Predicting acid or base strength from the conjugate
Order these chemical species by increasing pH of an 0.1 M aqueous solution of each. That is, imagine making an 0.1 M solution of each species. Select 1 next
to the species that makes the solution with the lowest pH. Select 2 next to the species that makes the solution with the next higher pH, and so on.
Notice that some of the rankings have been filled in for you already. Also notice that water is on the list. For that particular case, just compare the pH of pure
water to the pH of the other solutions.
Note for advanced students: for all charged species, you may assume the necessary counterions act as neither acids nor bases.
species
CH₂CH(OH) COOH
Explanation
H₂O
C6H5NH3
OH
C6H5O
CHẠNH,
CHOK
CH₂CH(OH)COO
Check
relative pH of
0.1 M aqueous solution
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Chapter 15 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 15.2 - For the reaction H2CO3(aq)+CN(aq)HCN(aq)+HCO3(aq)...Ch. 15.2 - Prob. 15.1CCCh. 15.3 - Identify the Lewis acid and the Lewis base in each...Ch. 15.4 - Prob. 15.3ECh. 15.4 - Prob. 15.2CCCh. 15.5 - Which member of each of the following pairs is the...Ch. 15.7 - A solution of barium hydroxide at 25C is 0.125 M...Ch. 15.7 - Prob. 15.6ECh. 15.7 - Rank the following solutions from most acidic to...Ch. 15.8 - What is the pH of a sample of gastric juice...
Ch. 15.8 - A saturated solution of calcium hydroxide has a...Ch. 15.8 - A brand of carbonated beverage has a pH of 3.16....Ch. 15.8 - A 0.010 M solution of ammonia, NH3, has a pH of...Ch. 15.8 - Prob. 15.4CCCh. 15 - Which of the following are strong acids? Which are...Ch. 15 - Describe any thermochemical (heat of reaction)...Ch. 15 - Prob. 15.3QPCh. 15 - Prob. 15.4QPCh. 15 - Write an equation in which H2PO3 acts as an acid...Ch. 15 - Describe four ways in which the BrnstedLowry...Ch. 15 - Prob. 15.7QPCh. 15 - Explain why an acidbase reaction favors the weaker...Ch. 15 - Give two important factors that determine the...Ch. 15 - Prob. 15.10QPCh. 15 - Prob. 15.11QPCh. 15 - Prob. 15.12QPCh. 15 - Prob. 15.13QPCh. 15 - Prob. 15.14QPCh. 15 - The conjugate base of hydrofluoric acid dissolved...Ch. 15 - In the following reaction, identify the Lewis...Ch. 15 - Calculate the hydronium-ion concentration at 25C...Ch. 15 - The pH of a solution is 9.55 at 25C What is the...Ch. 15 - Acids You make a solution by dissolving 0.0010 mol...Ch. 15 - Strong Acids, Weak Acids, and pH Two 0.10-mol...Ch. 15 - Prob. 15.21QPCh. 15 - Prob. 15.22QPCh. 15 - Prob. 15.23QPCh. 15 - Compare the structures of HNO2 and H2CO3. Which...Ch. 15 - Prob. 15.25QPCh. 15 - Prob. 15.26QPCh. 15 - A strong monoprotic acid, with the molecular...Ch. 15 - A weak acid, HA, is dissolved in water. Which one...Ch. 15 - Write the balanced reaction of hydroxide ion with...Ch. 15 - Write the balanced reaction of hypobromous acid,...Ch. 15 - Give the conjugate base to each of the following...Ch. 15 - Give the conjugate base to each of the following...Ch. 15 - Give the conjugate acid to each of the following...Ch. 15 - Give the conjugate acid to each of the following...Ch. 15 - For the following reactions, label each species as...Ch. 15 - For the following reactions, label each species as...Ch. 15 - The following shows ball-and-stick models of the...Ch. 15 - The following shows ball-and-stick models of the...Ch. 15 - Complete each of the following equations. Then...Ch. 15 - Complete each of the following equations. Then...Ch. 15 - In the following reactions, identify each reactant...Ch. 15 - In the following reactions, label each reactant as...Ch. 15 - Natural gas frequently contains hydrogen sulfide,...Ch. 15 - Coal and other fossil fuels usually contain sulfur...Ch. 15 - Complete the following equation. Using Table 15.2,...Ch. 15 - Complete the following equation. Using Table 15.2,...Ch. 15 - Use Table 15.2 to decide whether the species on...Ch. 15 - Use Table 15.2 to decide whether the species on...Ch. 15 - Prob. 15.49QPCh. 15 - In the following reaction of tetrafluoroboric...Ch. 15 - For each of the following pairs, give the stronger...Ch. 15 - Order each of the following pairs by acid...Ch. 15 - What are the concentrations of H3O+ and OH in each...Ch. 15 - What are the concentrations of H3O+ and OH in each...Ch. 15 - A solution of hydrochloric acid is 0.059 M HCl....Ch. 15 - A solution is 0.030 M HNO3 (nitric acid). What is...Ch. 15 - What are the hydronium-ion and the hydroxide-ion...Ch. 15 - A saturated solution of magnesium hydroxide is 3.2...Ch. 15 - The following are solution concentrations....Ch. 15 - The following are solution concentrations....Ch. 15 - A shampoo solution at 25C has a hydroxide-ion...Ch. 15 - An antiseptic solution at 25C has a hydroxide-ion...Ch. 15 - Which of the following pH values indicate an...Ch. 15 - Which of the following pH values indicate an...Ch. 15 - For each of the following, state whether the...Ch. 15 - Prob. 15.66QPCh. 15 - Obtain the pH corresponding to the following...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - A sample of vinegar has a hydronium-ion...Ch. 15 - Some lemon juice has a hydronium-ion concentration...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - A solution of washing soda (sodium carbonate,...Ch. 15 - A solution of lye (sodium hydroxide, NaOH) has a...Ch. 15 - The pH of a cup of coffee (at 25C) was found to be...Ch. 15 - A wine was tested for acidity, and its pH was...Ch. 15 - A detergent solution has a pH of 11.80 at 25C....Ch. 15 - Morphine is a narcotic that is used to relieve...Ch. 15 - A 1.00-L aqueous solution contained 5.80 g of...Ch. 15 - A 1.00-L aqueous solution contained 6.78 g of...Ch. 15 - A certain sample of rainwater gives a yellow color...Ch. 15 - A drop of thymol blue gave a yellow color with a...Ch. 15 - Identify each of the following as an acid or a...Ch. 15 - Which of the following substances are acids in...Ch. 15 - Write a reaction for each of the following in...Ch. 15 - Write a reaction for each of the following in...Ch. 15 - Prob. 15.87QPCh. 15 - Prob. 15.88QPCh. 15 - Prob. 15.89QPCh. 15 - Prob. 15.90QPCh. 15 - Prob. 15.91QPCh. 15 - List the following compounds in order of...Ch. 15 - A solution is 0.18 M KOH. What are the...Ch. 15 - A solution is 0.25 M Sr(OH)2. What are the...Ch. 15 - Prob. 15.95QPCh. 15 - A sample of lemon juice has a hydronium-ion...Ch. 15 - Prob. 15.97QPCh. 15 - A sample of grape juice has a pH of 4.15. What is...Ch. 15 - A 4.640-g sample of a mixture of sodium hydrogen...Ch. 15 - A 2.500-g sample of a mixture of sodium carbonate...Ch. 15 - Prob. 15.101QPCh. 15 - The dihydrogen phosphate ion has the ability to...Ch. 15 - Prob. 15.103QPCh. 15 - Prob. 15.104QPCh. 15 - Prob. 15.105QPCh. 15 - Show how methylamine, CH3NH2, is a BrnstedLowry...Ch. 15 - Prob. 15.107QPCh. 15 - Prob. 15.108QPCh. 15 - Prob. 15.109QPCh. 15 - Prob. 15.110QPCh. 15 - Prob. 15.111QPCh. 15 - Hydrazine, N2H4 (having the structure H2NNH2), and...Ch. 15 - Prob. 15.113QPCh. 15 - Liquid ammonia undergoes autoionization similar to...Ch. 15 - Ethanol (ethyl alcohol), CH3CH2OH, can act as a...Ch. 15 - Ethanol, CH3CH2OH, can undergo auto-ionization....Ch. 15 - Aluminum chloride, AlCl3, reacts with...Ch. 15 - Consider each of the following pairs of compounds,...Ch. 15 - Arrange each of the following in order of...Ch. 15 - The following is a table of some of the oxoacids...Ch. 15 - Suppose you have 557 mL of 0.0300 M HCl, and you...Ch. 15 - Prob. 15.122QPCh. 15 - You want to make up 3.00 L of aqueous hydrochloric...Ch. 15 - Prob. 15.124QPCh. 15 - Prob. 15.125QPCh. 15 - Pure liquid ammonia ionizes in a way similar to...Ch. 15 - A solution contains 4.25g of ammonia per 250.0 mL...Ch. 15 - A solution contains 0.675 g of ethylamine,...Ch. 15 - Prob. 15.129QPCh. 15 - Hypophosphorous acid, H3PO2, and phosphoric acid,...Ch. 15 - Boron trifluoride, BF3, and ammonia, NH3, react to...Ch. 15 - Boron trifluoride, BF3, and diethyl ether,...
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