Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Textbook Question
Chapter 14, Problem 14.75QE
Calculate the solubility of barium sulfate (Ksp = 1.1 × 10−10) in
- (a) water.
- (b) a 0.10 M barium chloride solution.
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The separate samples of nitric and acetic acids are both titrated with a 0.100 M solution of NaOH(aq).
(Y) 25.0mL of 1.0 M HNO3(aq) (Z) 25.0 mL of 1.0 M CH3COOH(aq)
Determine whether each of the following statements concerning this titration is true or false.
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(C) Phenolphthalein would be a suitable indicator for both titrations
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Because barium sulfate is opaque to X-rays, it is suspended in water and taken internally to make the gastrointestinal tract visible in an X-ray photograph. Although barium ion is quite toxic, barium sulfate’s Ksp of 1.1 x 10–10 gives it such low solubility that it can be safely consumed.
(a) What is the molar solubility of BaSO4?
(b) What is its solubility in grams per 100 g of water?
The solubility product for calcium phosphate is Ksp= 1.3 × 10–26. What is the molar solubility of calcium phosphate?
Chapter 14 Solutions
Chemistry: Principles and Practice
Ch. 14 - Prob. 14.1QECh. 14 - Describe a nonchemical system that is in...Ch. 14 - Describe a nonchemical system that is not in...Ch. 14 - Prob. 14.4QECh. 14 - Prob. 14.5QECh. 14 - Prob. 14.6QECh. 14 - Prob. 14.7QECh. 14 - Prob. 14.8QECh. 14 - Prob. 14.9QECh. 14 - Prob. 14.10QE
Ch. 14 - Explain why terms for pure liquids and solids do...Ch. 14 - Temperature influences solubility. Does...Ch. 14 - Prob. 14.13QECh. 14 - Prob. 14.14QECh. 14 - Prob. 14.15QECh. 14 - Prob. 14.16QECh. 14 - Prob. 14.17QECh. 14 - Prob. 14.18QECh. 14 - At 2000 K, experiments show that the equilibrium...Ch. 14 - At 500 K, the equilibrium constant is 155 for...Ch. 14 - At 77 C, Kp is 1.7 104 for the formation of...Ch. 14 - Consider the following equilibria involving SO2(g)...Ch. 14 - Kc at 137 C is 4.42 for NO(g) + 12 Br2(g) NOBr(g)...Ch. 14 - Prob. 14.24QECh. 14 - Prob. 14.25QECh. 14 - Prob. 14.26QECh. 14 - Prob. 14.27QECh. 14 - Prob. 14.28QECh. 14 - Prob. 14.29QECh. 14 - Prob. 14.30QECh. 14 - Prob. 14.31QECh. 14 - Prob. 14.32QECh. 14 - Prob. 14.33QECh. 14 - Prob. 14.34QECh. 14 - Prob. 14.35QECh. 14 - Consider the system...Ch. 14 - Prob. 14.37QECh. 14 - Prob. 14.38QECh. 14 - Prob. 14.39QECh. 14 - Prob. 14.40QECh. 14 - Prob. 14.41QECh. 14 - Prob. 14.42QECh. 14 - Prob. 14.43QECh. 14 - Prob. 14.44QECh. 14 - Prob. 14.45QECh. 14 - Prob. 14.46QECh. 14 - Prob. 14.47QECh. 14 - Prob. 14.48QECh. 14 - Prob. 14.49QECh. 14 - Prob. 14.50QECh. 14 - Prob. 14.51QECh. 14 - Consider 0.200 mol phosphorus pentachloride sealed...Ch. 14 - Prob. 14.53QECh. 14 - Prob. 14.54QECh. 14 - Prob. 14.55QECh. 14 - Prob. 14.56QECh. 14 - Prob. 14.57QECh. 14 - Prob. 14.58QECh. 14 - Prob. 14.59QECh. 14 - Prob. 14.60QECh. 14 - Prob. 14.61QECh. 14 - Write the expression for the equilibrium constant...Ch. 14 - Prob. 14.63QECh. 14 - Prob. 14.64QECh. 14 - Write the expression for the solubility product...Ch. 14 - Prob. 14.66QECh. 14 - Prob. 14.67QECh. 14 - The solubility of silver iodate, AgIO3, is 1.8 ...Ch. 14 - Prob. 14.69QECh. 14 - Prob. 14.70QECh. 14 - Prob. 14.71QECh. 14 - Prob. 14.72QECh. 14 - Even though barium is toxic, a suspension of...Ch. 14 - Lead poisoning has been a hazard for centuries....Ch. 14 - Calculate the solubility of barium sulfate (Ksp =...Ch. 14 - Calculate the solubility of copper(II) iodate,...Ch. 14 - Calculate the solubility of lead fluoride, PbF2...Ch. 14 - Calculate the solubility of zinc carbonate, ZnCO3...Ch. 14 - Prob. 14.79QECh. 14 - Prob. 14.80QECh. 14 - Use the solubility product constant from Appendix...Ch. 14 - Prob. 14.82QECh. 14 - Some barium chloride is added to a solution that...Ch. 14 - Prob. 14.84QECh. 14 - Prob. 14.85QECh. 14 - Prob. 14.86QECh. 14 - Prob. 14.87QECh. 14 - Prob. 14.88QECh. 14 - Prob. 14.89QECh. 14 - Prob. 14.90QECh. 14 - Prob. 14.91QECh. 14 - At 3000 K, carbon dioxide dissociates CO2(g) ...Ch. 14 - Prob. 14.94QECh. 14 - Nitrogen, hydrogen, and ammonia are in equilibrium...Ch. 14 - The concentration of barium in a saturated...Ch. 14 - According to the Resource Conservation and...Ch. 14 - Prob. 14.98QE
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- Calculate the solubility in grams per 100 mL of BaF2 in a 0.10 M BaCl2 solution.arrow_forwardThe Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)arrow_forwardAccording to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?arrow_forward
- Lead (II) chloride, PbCl2, has Ksp = 1.6 x 10–5. (a) Determine the solubility of PbCl2 expressed in mol/L; (b) How many grams of PbCl2 will dissolve in 250 mL of water? (c) Predict whether PbCl2 precipitate will be formed when 2.0 mL of 0.10 M Pb(NO3)2 is added to 3.0 mL of 0.10 M NaCl.arrow_forwardThe thermodynamic solubility product of AGCN is 6.0x10-17. (a) What is [Ag+] in a 0.033 M KNO3 solution? 4.0 7.7e-9 X mol·L-1 (b) What is [Ag+] in a 0.033 M KCN solution? 4.0 1.8e-15 X mol·L-1arrow_forwardThe thermodynamic solubility product of A9CN is 6.0×10-17. (a) What is [Ag+] in a 0.033 M KNO3 solution? 4.0 7.75e-9 mol·L-1 (b) What is [Ag+] in a 0.033 M KCN solution? 4.0 1.81e-16 X mol·L-1arrow_forward
- The solubility product, Ksp, of PbCl2 is 1.6 × 10-5. What mass of KCl(s) must be dissolved in 150.00 mL of 1.15M Pb(NO3)2 to produce a solution that is just saturated in PbCl2?arrow_forwardComplete the following solubility constant expression for Co(OH)2. K = sp X Śarrow_forwardThe solubility product constant for Ba(IO3)2 at 30.0°C is 7.8 x 10^-9. Determine the molar solubility if 65.0 g of Ba(NO3)2 is dissolved in 2.5 L of a Ba(IO3)2 saturated solution.arrow_forward
- 1.1The Ksp of Ca3 (PO4 ) 2 is 1.3 × 10−26 . Estimate the solubility of this salt in units of g. L −1 . You must show any reaction equation(s) that you may think are necessary. 1.2 If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 1.1? Explain you answer in a short sentence.arrow_forwardA solution contains 1.48 10 M barium acetate and 6.82x10 M calcium nitrate. Solid potassium sulfate is added slowly to this mixture. What is the concentration of barium ion when calcium ion begins to precipitate? [Ba =| Marrow_forwardSodium phosphate is added to a solution that contains 0.0014 M aluminum nitrate and 0.028 M calcium chloride. The concentration of the first ion to precipitate (either Al or Ca") decreases as its precipitate forms. What is the concentration of this ion when the second ion begins to precipitate?arrow_forward
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