Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 11.5, Problem 8P

Using the pKa values listed in Table 11.1, predict the products of the following reactions:

Chapter 11.5, Problem 8P, Using the pKa values listed in Table 11.1, predict the products of the following reactions: , example  1

Chapter 11.5, Problem 8P, Using the pKa values listed in Table 11.1, predict the products of the following reactions: , example  2

Chapter 11.5, Problem 8P, Using the pKa values listed in Table 11.1, predict the products of the following reactions: , example  3

Chapter 11.5, Problem 8P, Using the pKa values listed in Table 11.1, predict the products of the following reactions: , example  4

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Maleic anhydride may be prepared using two routes: Oxidation of benzene: Oxidation of but-1-ene: 76 +30₂ + 2COz + 2H,O + 3 H₂O The benzene oxidation route typically occurs in 65 % yield, while the but-1- ene route only gives yields of 55 %. (a) Assuming that each reaction is performed in the gas phase only, and that no additional chemicals are required, calculate (i) the atom economy and (ii) the effective mass yield of both reactions. You should assume that O₂, CO₂ and H₂O are not toxic. (b) Which route would you recommend to industry? Outline the factors which might influence your decision.
How do you determine which reaction is thermodynamically favorable using pka values?

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Essential Organic Chemistry (3rd Edition)

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