Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Textbook Question
Chapter 1, Problem 22PP
Practice Problem 1.22
Which of the following
(a)
(b)
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This question is about the chemistry of alkenes, which are unsaturated hydrocarbons.
(a) State what is meant by the term unsaturated as applied to a hydrocarbon.
(1)
(b) An organic compound, X, is an unsaturated hydrocarbon with molecular formula
CH₂.
(i) Draw the displayed formulae and give the names of two molecules with
molecular formula C₂H, which are E/Z isomers.
(3)
Isomer 1
Isomer 2
Name:
Name:
1. (A) DRAW are all the possible isomers for dibromobutane and the cylic isomers for C3H4Br2
(B) WRITE THE STRUCTURAL OR CONDENSED FORMULAR FOR
C3H7Br
C3H6Br2
C3H5Br3
C5H11Br
(a) The compound given below had the following IUPAC name and structural formula dibromocyclopentane C3H6CHBrCHBr (i) What type of isomerism is possible in the organic compound? (ii) Draw all the pairs of possible isomers and name them.
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - Prob. 1PPCh. 1 - Prob. 2PPCh. 1 - Prob. 3PPCh. 1 - Prob. 4PPCh. 1 - Prob. 5PPCh. 1 - Prob. 6PPCh. 1 - Prob. 7PPCh. 1 - Prob. 8PPCh. 1 - Prob. 9PPCh. 1 - Prob. 10PP
Ch. 1 - Prob. 11PPCh. 1 - Prob. 12PPCh. 1 - Prob. 13PPCh. 1 - Prob. 14PPCh. 1 - Prob. 15PPCh. 1 - Prob. 16PPCh. 1 - Prob. 17PPCh. 1 - Prob. 18PPCh. 1 - Prob. 19PPCh. 1 - Prob. 20PPCh. 1 - Prob. 21PPCh. 1 - Practice Problem 1.22 Which of the following...Ch. 1 - Prob. 23PPCh. 1 - Prob. 24PPCh. 1 - Practice Problem 1.25
What do the bond angles of...Ch. 1 - Prob. 26PPCh. 1 - Practice Problem 1.27
Use VSEPR theory to predict...Ch. 1 - Practice Problem 1.28 Predict the bond angles of...Ch. 1 - 1.29 Which of the following ions possess the...Ch. 1 - 1.30 Write a Lewis structure for each of the...Ch. 1 - Prob. 31PCh. 1 - Add any unshared electrons to give each element an...Ch. 1 - Prob. 33PCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - 1.37 Write bond-line formulas for all of the...Ch. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - (a) Cyanic acid (HOCN) and isocyanic acid (HN=C=O)...Ch. 1 - Consider a chemical species (either a molecule or...Ch. 1 - 1.44 Consider a chemical species like the one in...Ch. 1 - 1.45 Consider another chemical species like the...Ch. 1 - Draw a three-dimensional orbital representation...Ch. 1 - Ozone (O3) is found in the upper atmosphere where...Ch. 1 - Write resonance structures for the azide ion, N3....Ch. 1 - Write structural formulas of the type indicated:...Ch. 1 - Prob. 50PCh. 1 - 1.51 In Chapter 15 we shall learn how the...Ch. 1 - Prob. 52PCh. 1 - (a) Consider a carbon atom in its ground state....Ch. 1 - Open computer molecular models for dimethyl ether,...Ch. 1 - Boron is a group IIIA element. Open the molecular...Ch. 1 - 1.56 There are two contributing resonance...Ch. 1 - Prob. 1LGPCh. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Prob. 7LGPCh. 1 - Prob. 8LGP
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- (a) Draw the nine isomers having the formula C7H16 . (Hint: There is one structure with a seven-carbon chain, two structures with six-carbon chains [one is illustrated in the margin above], five structures with a five-carbon chain, and one structure with a fourcarbon chain.)(b) Identify the isomers of C7H16 that are chiral.arrow_forward(a) What is meant by the term isomer ? (b) Among the four alkanes, ethane, propane, butane, and pentane, which is capable of existing in isomeric forms?arrow_forwardQuestion B2 Below is given the structure of 1,1-dimethylcyciohexane CH3 CHS (a) Using the chair representation, draw the two possible conformers of 1,1- dimethylcyclohexane. (b) Is one conformer preferred over the other? Justify your answer. (c) One of the CH, groups is replaced with a sec-butyl group and the structure of this new molecule is given below. CH3 CH(CH,)CH,CH, Draw the two possible chair conformers, and using equilibrium arrows, indicate if there is a preferred conformation. Justify your answer. orarrow_forward
- An alkane, P, has the molecular formula, C,H.. An alkene, Q, has the molecular formula, C H,. (a) Name P and Q ánd write their full structural formulae. (b) State two differences between P and Q in terms of their structures. x'arrow_forward2.25 A certain hydrocarbon has a molecular formula of C5 Hg. Which of the following is not a structural possibility for this hydrocarbon? (a) It is a cycloalkane. (b) It contains one ring and one double bond. (c) It contains two double bonds and no rings. (d) It is an alkyne.arrow_forward3 (a) Give the structural formulae of all the chain isomers of C5H12. (b) Give two position isomers of the molecule that has the following molecular formula: C-H₁0 (c) Give the two functional group isomers having the molecular formula: C₂H₂Oarrow_forward
- Classify each of he following hydrocarbons as alkanes, alkenes, or alkynes. (a) C6H14 (b) C3H4 (c) C9H18arrow_forwardIndicate whether each statement is true or false. (a) Twogeometric isomers of pentane are n-pentane and neopentane.(b) Alkenes can have cis and trans isomers around theCC double bond. (c) Alkynes can have cis and trans isomersaround the CC triple bond.arrow_forwardThe skeletal line formula for a branched alkene is shown below. (i) What is the molecular formula of this compound? (ii) How many carbon atoms are in the longest chain, ignoring the double bond? (iii) What is the longest chain incorporating both carbons of the double bond? (iv) How many substituents are on this chain? (v) Give the IUPAC name for this compound. [6]arrow_forward
- Draw the skeletal structure of the following organic molecules. (i) 4-chloropentanal (ii) 2,3-dimethylbutan-1-ol (iii) CH3CH(OH)CH₂CN (you can leave the nitrile group as -CN) Name the organic molecules shown below. (i) (CH3)2C=CHCH₂CH3arrow_forwardA saturated alkanol X has the relative molecular mass of 74.0. (a) Give the general formula of alkanol. (b)(i) Deduce the molecular formula of X. (Relative atomic mass of C=12, H=1, O=16) (c)(i) X is optically active. Draw the two enantiomers of X. (ii) Name X.arrow_forwardWhich of the following substances exist as can cis–trans isomers? Draw both isomers for those that do.(a) 2,3-Dimethylpent-2-ene (condensed structures only)(b) 2-Methylhex-2-ene (both condensed and line structures)(c) Hex-2-ene (line structures only)arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License