Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Question
Chapter 1, Problem 1.13CP
Interpretation Introduction
Interpretation:
The conditions at which the wall (if movable piston) will move due to molecular collisions needs to be explained.
Concept Introduction:
The theory of collision explains that for a
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How can the number of effective collisions be increased?
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Chapter 1 Solutions
Thermodynamics, Statistical Thermodynamics, & Kinetics
Ch. 1 - Real walls are never totally adiabatic. Use your...Ch. 1 - The parameter a in the van der Waals equation is...Ch. 1 - Give an example based on molecule—molecule...Ch. 1 - Prob. 1.4CPCh. 1 - Prob. 1.5CPCh. 1 - The location of the boundary between the system...Ch. 1 - Prob. 1.7CPCh. 1 - At sufficiently high temperatures, the van der...Ch. 1 - Prob. 1.9CPCh. 1 - Prob. 1.10CP
Ch. 1 - Prob. 1.11CPCh. 1 - Prob. 1.12CPCh. 1 - Prob. 1.13CPCh. 1 - The mass of a He atom is less than that of an Ar...Ch. 1 - Prob. 1.15CPCh. 1 - Prob. 1.1NPCh. 1 - A compressed cylinder of gas contains 2.74103g of...Ch. 1 - Calculate the pressure exerted by Ar for a molar...Ch. 1 - A sample of propane C3H8 is placed in a closed...Ch. 1 - A gas sample is known to be a mixture of ethane...Ch. 1 - One liter of fully oxygenated blood can carry 0.18...Ch. 1 - Yeast and other organisms can convert glucose...Ch. 1 - A vessel contains 1.15 g liq H2O in equilibrium...Ch. 1 - Consider a 31.0 L sample of moist air at 60.C and...Ch. 1 - Prob. 1.10NPCh. 1 - Prob. 1.11NPCh. 1 - A rigid vessel of volume 0.400m3 containing H2 at...Ch. 1 - A mixture of oxygen and hydrogen is analyzed by...Ch. 1 - An athlete at high performance inhales 3.75L of...Ch. 1 - Devise a temperature scale, abbreviated G, for...Ch. 1 - Aerobic cells metabolize glucose in the...Ch. 1 - Prob. 1.17NPCh. 1 - A mixture of 2.10103g of O2, 3.88103mol of N2, and...Ch. 1 - Prob. 1.19NPCh. 1 - Prob. 1.20NPCh. 1 - An initial step in the biosynthesis of glucose...Ch. 1 - Prob. 1.22NPCh. 1 - Assume that air has a mean molar mass of 28.9gmol1...Ch. 1 - When Julius Caesar expired, his last exhalation...Ch. 1 - Calculate the number of molecules per m3 in an...Ch. 1 - Prob. 1.26NPCh. 1 - A mixture of H2 and NH3 has a volume of 139.0cm3...Ch. 1 - A sealed flask with a capacity of 1.22dm3 contains...Ch. 1 - A balloon filled with 11.50 L of Ar at 18.7C and 1...Ch. 1 - Carbon monoxide competes with oxygen for binding...Ch. 1 - The total pressure of a mixture of oxygen and...Ch. 1 - Suppose that you measured the product PV of 1 mol...Ch. 1 - Liquid N2 has a density of 875.4kgm3 at its normal...Ch. 1 - Calculate the volume of all gases evolved by the...Ch. 1 - Prob. 1.35NPCh. 1 - A glass bulb of volume 0.198 L contains 0.457 g of...Ch. 1 - Prob. 1.37NPCh. 1 - Prob. 1.38NPCh. 1 - Many processes such as the fabrication of...Ch. 1 - Rewrite the van der Waals equation using the molar...
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Similar questions
- Consider a gas mixture containing equal concentrations of argon and helium. Without performing any calculations, determine which is higher: the number of collisions between helium and helium, the number of collisions between argon and argon, or the number of collisions between helium and argon?arrow_forwardUse equation 4.46 as an example and find an expression for A as the volume varies.arrow_forward5. Consider air (which consists of 79 mol% of N2 and 21 mol% of O2) at 300 K: (a) What is the self-collision rate of nitrogen molecules in number of collisions per m' per second? (b) What is the self-collision rate of oxygen molecules in number of collisions per m' per second? (c) What is the collision rate between oxygen and nitrogen molecules in number of collisions per m' per second? Hint: Use the hard-sphere model where all the collisions are effective. The diameters of oxygen molecules and nitrogen molecules are 3.61 Å and 3.75 Å, respectively. For self-collision scenarios, calculate reduced mass based on two molecules of the same size and mass and be mindful that the number of collisions is double counted.arrow_forward
- A mixture of ideal gases having a total mass of 35 g is placed in a 13 L vessel at 269.0 K. The equilibrium pressure is measured to be 1.6 bar. Calculate the average molar mass of the gas mixture.arrow_forwardThe total energy of two colliding gas molecules is conserved because the Group of answer choices collision is inelastic. collision is elastic. collision intensity varies as temperature changes. collision occurs too rapidly for energy to be lost.arrow_forwardDetermine the final pressure of the system (i.e. after the reaction has occurred) if 45.2 grams of gaseous nitrogen are allowed to react with 252 grams of gaseous chlorine to produce liquid nitrogen trichloride according to the reaction below. The reaction takes place in a 11.5 L container at a temperature of 319 K. Assume that the liquid has 0 vapor pressure and takes up a negligible amount of volume. Report the value of your pressure in atm (do not include units in the answer field). N2 (g) + 3 Cl2 (g) --> 2 NC13 (1)arrow_forward
- O2 (g) effuses at a rate that is how many times that of Cl2 (g) under the same conditions?arrow_forwardGive some examples of molecular collisions of gases and state its applications.arrow_forwardthe speed of particles, thus the Adding ice to food has the effect of likelihood of particle collisions. I.arrow_forward
- All collisions (in chemistry) involving gases are considered to be elastic collisions. True Falsearrow_forwardCalculate the average translational kinetic energy, ?k,Ek, for one mole of gas at 605 K.605 K. Translational kinetic energy is sometimes called average kinetic energy. Calculate the average translational kinetic energy for a single gas molecule at 605 K.arrow_forwardcalculate the average translational kinetic energy, Ek, for one mole of gas as 553 K. Transitional kinetic energy is sometimes called average kinetic energy Ek = ? J/mol calculate the average translational kinetic energy for a single gas molecule as 553 K Ek = J/molarrow_forward
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