The substance to be analyzed – is deep-pink colored, highly soluble in water salt. Reaction with NH; gives blue-colored precipitate, which can be dissolved in NH3 surplus accompanied by dirty-yellow colored solution formation. After precipitation of cation by "sodium carbonate drawing out" method, supernatant was independently treated by silver nitrate solution and barium chloride solution (in acid medium in both cases) – any precipitation hasn't been observed. Addition of antipyrin in acid medium changes color to red. What kind of substance is this? Co(NO3)2 CuCl, Co(CH;COO), FeSO4
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- In this activity, you will develop an experimental procedure to solve a problem. Consider the followingscenario:You are the manager of a chemical stockroom, and find a bottle containing approximately one liter of aclear and colorless solution of unknown identity and concentration. Your only clue to its identity is thatit was found between bottles of silver fluoride and sodium fluoride, so it is likely an aqueous solution ofone of those two compounds. You will need to develop a procedure to determine the following:a) The identity of the unknown solutionb) The concentration of the unknown solutionWrite out a precise procedure, which includes all glassware, reagents, and steps. You will also need towrite the calculations that you would need to determine the concentration of the solution. Assume thatyou have access to any reagent you might need(a) Halogen, V reacts with hydrogen gas to form HV only when heated to 200 °C in the presence of a platinum catalyst. An aqueous solution of HV is formed when HV is dissolved in water. When aqueous silver nitrate solution is added to the HV solution, precipitate W is formed. With the aid of a balanced chemical equation, explain the reaction between precipitate W and concentrated ammonia solution. () (i) The melting point of hydrogen fluoride, HF is higher than HV. Explain this phenomenon in terms of structure and bonding.A pink solid has the formula CoCl3 5NH3 H2O. A solution of this salt is also pink and rapidly precipitates 3mol AgCl(s) on titration with silver nitrate solution. When the pink solid is heated, it loses 1mol H2O to give a purple solid with the same mole ratio of NH3:Cl:Co as the pink solid. The purple solid releases two of its chloride ions rapidly; then on dissolution and titration with AgNO3, release one of its chloride ions slowly. Deduce the structures, draw and name 2 octhahedral complexes
- A solution containing a mixture of metal cations was treated with dilute HCl and a precipitate formed. The solution was filtered and H,S was bubbled through the acidic solution. A precipitate again formed and was filtered off. Then, the pH was raised to about 8 and H2S was again bubbled through the solution. This time, no precipitate formed. Finally, the solution was treated with a sodium carbonate solution, which resulted in the formation of a precipitate. Classify the metal ions based on whether they were definitely absent from the original mixture or whether it is possible they were present in the original mixture? Definitely absent Possibly present Ag+ Cu2+ Ba2+ Mn2+ Ni2+ AB+ Lit Sn++ Mg2+ Hg2+ Sb3+ Hg2+ Pb2+38 39 40 41 42 43 44 45 12- When dissolving iron in diluted hydrochloric acid, then adding NaOH Solution to the products. 1- The formed precipitate is ... (a) White gelatinous dissolve in sodium hydroxide solution. (b) Reddish brown precipitate dissolves in diluted hydrochloric acid (C) Pale green precipitate dissolves in diluted hydrochloric acid (d) Pale green precipitate dissolves in sodium hydroxide solution.A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H,S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly present Cd²+ Ag* Ba2+ Mn2+ Mg2+ Fe2+ A13+ Pb2+ Sn2+ Lit Hg3* Hg²+ Sb3+ Answer Bank
- A solution that may contain Cu2+ , Bi2+ , Sn4+ , or Sb2+ is treated with thioacetamide in an acidic medium. The black precipitate which forms is partly soluble in strongly basic solution. The precipitate which remains is soluble in 6 M HNO3 and gives only a white precipitate upon the addition of NH4OH. The basic solution, when acidified, produces an orange precipitate. Which group II ions are present? Which are absent? Which are in doubt? How would you remove all doubt?A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H, S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly present Answer Bank Hg3+ Pb2+ Lit Bj³+ Sn2+ Ni2+ A13+ Ag* Zn2+ Ba2+ Mg2+ Hg²+ Cu?+A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H,S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H,S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly present Answer Bank Sn2+ Ag* Hg²+ Sb3+ Pb2+ Ba2+ Cu²+ Mg2+ Zn²+ Ni2+ Co²+ K+ Hg3+
- A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H,S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly presentA solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H, S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly present Ag* Hg²+ Lit Ba²+ Pb2+ Mg²+ Hg3* 2+ Answer Bank Zn2+ Sn2+ Ni2+ Cu2+ Bi3+ A13+ IncorrectA solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H,S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H, S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly present Answer Bank Bi3+ Cu²+ Ni?+ Lit Ag+ Sn2+ Pb2+ A13+ Ba2+ Zn²+ Hg²+ Mg?+ Hgž+