A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H,S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture.

Fundamentals Of Analytical Chemistry
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Author:Skoog
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Chapter14: Principles Of Neutralization Titrations
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Problem 14.8QAP
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A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled
through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H,S was again
bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium
carbonate solution, which resulted in no precipitation.
Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were
present in the original mixture.
Definitely present
Definitely absent
Possibly present
Cd²+
Ag*
Ba2+
Mn2+
Mg2+
Fe2+
A13+
Pb2+
Sn2+
Lit
Hg3*
Hg²+
Sb3+
Answer Bank
Transcribed Image Text:A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H, S was bubbled through the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H,S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Classify the metal ions based on whether they were definitely present, definitely absent, or whether it is possible they were present in the original mixture. Definitely present Definitely absent Possibly present Cd²+ Ag* Ba2+ Mn2+ Mg2+ Fe2+ A13+ Pb2+ Sn2+ Lit Hg3* Hg²+ Sb3+ Answer Bank
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