The solubility of CaCO3 in water is about 7 mg L-1 . Show how one can calculate the solubility product of BaCO3 from this information and from the fact that when sodium carbonate solution is added slowly to a solution containing equimolar concentrations of Ca2+ and Ba2+, no CaCO3 is formed until about 90% of the Ba2+ has been precipitated as BaCO3.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
Section: Chapter Questions
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The solubility of CaCO3 in water is about 7 mg L-1 . Show how one can calculate the solubility product of BaCO3 from this information and from the fact that when sodium carbonate solution is added slowly to a solution containing equimolar concentrations of Ca2+ and Ba2+, no CaCO3 is formed until about 90% of the Ba2+ has been precipitated as BaCO3.

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