The gas-phase basicity of triphenylamine (876.4 kJ mol-1) is less than that of triphenylphosphine (940.4 kJ mol-1). Write an equation to represent each reaction. Do you expect electronic or steric factors to contribute more to this difference? Explain

The gas-phase basicity of triphenylamine (876.4 kJ mol-1) is less than that of triphenylphosphine (940.4 kJ mol-1). Write an equation to represent each reaction. Do you expect electronic or steric factors to contribute more to this difference? Explain

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.31P

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Question

The gas-phase basicity of triphenylamine (876.4 kJ mol-1) is less than
that of triphenylphosphine (940.4 kJ mol-1). Write an equation to
represent each reaction. Do you expect electronic or steric factors to
contribute more to this difference? Explain

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