Suppose also k₁»k₂. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: 0 Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of K₁, K2, and (if necessary) the rate constants k-1 and k-2 for the reverse of the two elementary reactions in the mechanism. rate = k = 0 k =

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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Suppose the decomposition of ozone proceeds by the following mechanism:
step
elementary reaction
rate constant
1
03(g)
O₂(g) + 0(g)
k₁
2
03(g) + O(g) →
20₂(g)
k₂
Suppose also k₁ »k₂. That is, the first step is much faster than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
rate = k
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of K₁, K2,
and (if necessary) the rate
constants k.1 and k-2 for
the reverse of the two
elementary reactions in
the mechanism.
= 0
k =
00
X
5
S ?
Transcribed Image Text:Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 03(g) O₂(g) + 0(g) k₁ 2 03(g) + O(g) → 20₂(g) k₂ Suppose also k₁ »k₂. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of K₁, K2, and (if necessary) the rate constants k.1 and k-2 for the reverse of the two elementary reactions in the mechanism. = 0 k = 00 X 5 S ?
Suppose also k₁»k₂. That is, the first step is much faster than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
0
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of K₁, K2,
and (if necessary) the rate
constants k-1 and k-2 for
the reverse of the two
elementary reactions in
the mechanism.
rate = k
k =
0-0
1
Olo
X
2
Transcribed Image Text:Suppose also k₁»k₂. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: 0 Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of K₁, K2, and (if necessary) the rate constants k-1 and k-2 for the reverse of the two elementary reactions in the mechanism. rate = k k = 0-0 1 Olo X 2
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