Predict the major product formed in the following reaction. H. CH3 ༑ NaO CH, CH3 O,CCH H. ,OH HO. Η ིམ ི་ Η CH 1) H CH3 2) ., CH, Major product H H₂CCO₂ CH H ི་ ཡ ི་ CH; 3) Η Η CH; 4)
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- a) Predict the main organic product (E-G) in the following reactions and the mechanism (E1, E2, SŅ1 or SN2) by which it is formed. CH3 CH;OH/ Heat E Br (CH,,Co° CH;CH,CH,CHBrCH; F Br CH;CH2" CH2CH2CH3 CH3OH ČH3A reaction sequence to accomplish the following transformation is: OH CH3 Jo OH (a) 1.KOtBu, fBuOH; 2. MCPBA; 3. H3O+ (b) 1. HBr; 2. NaOCH 3, CH3OH; 3. CH3COOOH, H3O+ (c) 1. KOtBu, tBuOH; 2. OSO4, H₂O2 (d)1. HBr; 2. KOtBu, tBuOH; 3. MCPBA; 4. H3O+Ethyl acetate is synthesized in a nonreacting solvent (not water) according to the following reaction: CH3 CO,H+ C2H;OH - CH3 CO,C2H5 + H20 К - 2.2 Acetic acid Ethanol Ethyl acetate For the following mixtures (a-d), will the concentration of H20 increase, decrease, or remain the same as equilibrium is established? a. [CH3 CO,C,H5] = 0.22 M , [H;O] = 0.10 M, [CH; CO,H] = 0.010 M, [C2H; OH] = 0.010 M O increase decrease remain the same b. [CH;CO2C,Hs] = 0.22 M , [H2O] = 0.0020 M, [CH;CO,H] = 0.0020 M , [C,Hs OH] = 0.10 M %3D %3D O increase decrease remain the same c. [CH3CO2C,H5] = 0.88 M , [H;O] = 0.12 M, [CH; CO,H] = 0.044 M , [C,Hs OH] = 6.0 M increase decrease O remain the same d. [CH CO,C,H,] — 44 М, [Н,0] 3 44 М, [CH,CO,H] — 0.88 M, [С,н,он] — 10.0 М O increase decrease remain the same e. What must the concentration of water be for a mixture with (CH3 CO2C2H3] = 2.0 M, [CH3 CO,H = 0.10 M, and [C;Hs OH] = 7.0 M to be at equilibrium? %3D %3D Concentration = M
- (c) What would be the product of the following reaction? H. CH3OH CH3 H+ OH H. CH3 A) OCH3 H. CH;O% OH B) CH3 CH;O,Ì OH H. C) "ICH3 H3C, H OH D) MOCH3 OH H. CH2 E) (d) When considering the mechanism of the following reaction, which of the following statements is true? HO. H2SO4 A) A molecule of water is lost. B) The mechanism involves an SN2 reaction. C) A free carbocation is formed. D) Both A and B are true. E) Both A and C are true.Following are the steps in the industrial synthesis of glycerin. Cl₂ A (C₂H5C1) heat (A) CH₂=CHCH₂ Propene (B) OH HOCH₂CHCH₂OH 1,2,3-Propanetriol (glycerol, glycerin) Provide structures for all intermediate compounds (A-D) and describe the type of mechanism by which each is formed. P.3 O ▼ O▾ + ▾ C (C₂H₂C1O₂) *% 1 NaOH, H₂O All hydrogen atoms are implied. Apply formal charges where appropriate. Omit lone pairs and radical electrons from your answer. You do not have to consider stereochemistry. * B (C₂H5O) Ca(OH)2 heat Cl₂, H₂O D (C₂H6O₂) H₂O, HCI ChemDoodleⓇ6. Reactions at the a Carbon - Mechanism reaction below. :Ö: + H :0 Ö: CH3 Provide a reasonable mechanism for the NaOH / H₂O :0° الله :
- с-НCI (1 drop) H. OCH2CH3 H2N NH2 O2N ethanol, reflux 1. major product 2. the most plausible mechanism plzConsider the reaction and answer the questions that follow. CH-CH2- CH2-I • CH,S° CH3- CH2- CH2-S– CH; + CH3-CH= CH2 Product A Product B O Explain which type or types of mechanisms (Sw1, SN2, E1, and E2) are applicable to this reaction. [") How can you increase the percentage of Product A? [ui) How can you obtain Product B as almost the only product? A. [i] SN2 & E2 [ii] Use better nucleophile [iii Use a non-nucleophilic base B. [i] SN2 & E2 [ii] Use higher Temperature [iii] Use a non- nucleophilic base C. [i] SN2 & E2 [ii] Use lower Temperature [iii] Use a non-nucleophilic base D. [i] SN1 & E1 [ii] Use lower Temperature [iii] Use a non-nucleophilic base13:34 all 4G O. What is the final product(s) of the following reaction? CH,OH [H,SO,) OA OH H,CO OB. OH но H,CO OCH major minor Oc но OCH D.None of the above Add a caption... > Status (Custom) +
- 12. In the hydrogenation reaction shown, which of the alkenes below would yield the observed products? H₂, Pd/C alkene + one diastereomer || III IV (A) I and II (B) II and III (C) IV and III (D) II and IV (E) I and III(1) MeO₂C CO₂Me (ii) (iii) H H₂C 1. Reagents 2. Reaction Conditions 3. Mechanism 1. Reagents 2. Reaction Conditions 3. Mechanism 1. Reagents 2. Reaction Conditions 3. Mechanism H₂C CH3 O OH OH Afla H₂C OMe122. For the following three step conversion of A to B, the appropriate sequence of reactions is A OH CAREER ENDEAVOUR B CHO (a) MnO₂; (CH₂OH),/p-TSA; PCC (b) PCC; MnO₂; (CH₂OH)₂/p-TSA; (c) PCC; (CH₂OH)₂/p-TSA; Jones' reagent (d) Jones' reagent; (CH₂OH)₂/p-TSA; MnO₂.