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- Draw the mechanism for the following reaction: Et - OH x+a CH3 CH₂ Et Edit the reaction by drawing all steps in the appropriate boxes and connecting them with reaction arrows. Add charges where needed. Electron-flow arrows should start on the electron(s) of an atom or a bond and should end on an atom, bond, or location where a new bond should be created.la t-Bvo-20 ic ca Don 41 No To PER 23 V C Me 12. Predict the reactant. D Br o SOCI pyndase (only product .00CH_CH, QCH, THI querrinnr
- TESO nBuli, THF, -78 °C then TBAF 84% Me Me (nBu)3Sn Ō... OTES HO Me HII Me H Me- OH cyclocitrinol 1.0% over 18 linear steps Me OHJators. aleacti ong 04 d 1. Predict the major Diels-Alder products of the reactions below. Indicate stereochemistry if applicable. Label the diene and dienophile. Ph. J Ph CI + * + H3CO OCH 3 CEN Pu C1 * CI осиз CH3 !!!!CENQ1. Give the structure(s) of the major organic produc(s) of A-H, Show stereochemistry if appropriate. Hz. Pd/C KMnO4. H0. B 1. BH, C 2. NoOH, H,02 C2. CH,OH D HCI E KI, H;PO, KMno HO". G H.
- 5) What is the type of the following reaction: CO,.Et hv Co,E E10,C [6T - 2m) Cyclonddition Cycloaddition [2T + 21] Cycloaddition [4 - 47) - [417- 2m) Cycloaddition个 个 U ← 1. (CH3)2CHMgBr 2. Neutralizing work-up Select to Draw 1 V Q 1. CH3CCNa 2. H3O+ Select to Draw MaPredit ds produc 1. Br ght 2.1-BuOK 38 Which represet soy depis 2mthyleyclohexeol where the wo ubatitum are S.BH, in THE 4 HO, NaOH (A) (m) CH (A) 1014 (B) BH CH OH (C) (D) (9 O он (D) 25. What radical interediate is fonmed in CHa this reaction? CH HC 2 HOOH H,C 30 Which molecules sre chiral? H. hv HO (m) COH Br (C) HO (D) HO V 26. Predict the product OH SOci II IV (A) 1,II, II, & IV (C) H& II pyridine (B) II, II, A IV (D) I1& IV (A) (B) CI 31. Explain why this synthetic route will not produce this product. şoCi 1) CHMgr 2) HHP (C) (D) SOCI H,HO heal Which reagents produce this transformation? 27. (A) The Grigrard reagent will not add to the ketone. OH HO. (B) The Grignard reagent will not add to the alcohol. (A) 1) LIAIH 2) H, H;0 (C) The Markovnikov rule will lead to a different product. (B) NABH,, HO (D) Acid catalyzed dehydration will lead to the formation of the more (C) PCC, CH,Cl; (D) KMNO, NaOH, H;O, heat thermodynamically stable alkene. What is the formal charge of oxygen in…
- Acceptable Mechanison? - Œ 50% a I Acceptable Mechanismy- Ph-= -Pr 10215, CH3CH2NH₂ ZonMy Go (31)Dtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxidePlease help with 4c, 4d, and 4e. We havent learned kaw of equivalents so please do 4c a different way. thank you